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Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP) Full article

Journal Australian Journal of Chemistry
ISSN: 0004-9425 , E-ISSN: 1445-0038
Output data Year: 2018, Volume: 71, Number: 5, Pages: 334-340 Pages count : 7 DOI: 10.1071/CH17570
Authors Audran Gerard 1 , Bagryanskaya Elena 2,3 , Edeleva Mariya 2,3 , Marque Sylvain R.A. 1,2 , Parkhomenko Dmitriy 2 , Tretyakov Evgeny 2,3 , Zhivetyeva Svetlana 2
Affiliations
1 (Данные Web of science) Aix Marseille Univ, ICR, CNRS, UMR 7273, Case 551,Ave Escadrille Normandie Niemen, F-13397 Marseille 20, France
2 (Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Lavrentjev Ave 9, Novosibirsk 630090, Russia
3 (Данные Web of science) Novosibirsk State Univ, 2 Pirogova St, Novosibirsk 630090, Russia

Abstract: Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)(2) (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90 degrees C.
Cite: Audran G. , Bagryanskaya E. , Edeleva M. , Marque S.R.A. , Parkhomenko D. , Tretyakov E. , Zhivetyeva S.
Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)
Australian Journal of Chemistry. 2018. V.71. N5. P.334-340. DOI: 10.1071/CH17570 WOS Scopus РИНЦ OpenAlex
Identifiers:
Web of science: WOS:000432826800003
Scopus: 2-s2.0-85047533641
Elibrary: 35535498
OpenAlex: W2789153460
Citing:
DB Citing
Web of science 17
Scopus 17
Elibrary 13
OpenAlex 17
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