Abstract: Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular -weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.

Cite: Edeleva M.V. , Marque S. , Bagryanskaya E.G.
Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization
Russian Chemical Reviews. 2018. V.87. N4. P.328-349. DOI: 10.1070/RCR4765 WOS Scopus OpenAlex

Original: Еделева М.В. , Марк С.Р. , Багрянская Е.Г.
Имидазолиновые и имидазолидиновые нитроксильные радикалы как регуляторы псевдоживой радикальной полимеризации по механизму обратимого ингибирования
Успехи химии/Uspekhi Khimii. 2018. Т.87. №4. С.328-349. DOI: 10.1070/RCR4765?locatt=label:RUSSIAN РИНЦ

Dates:

Published online:	Apr 27, 2018
Published print:	Apr 30, 2018

Identifiers:

Web of science:	WOS:000431973300002
Scopus:	2-s2.0-85046547464
OpenAlex:	W2777358528

Citing:

DB	Citing
Web of science	23
Scopus	24
OpenAlex	25

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