Synthesis of (6,7-Dichlorononafluoro-5,6,7,8-tetrahydronaphthalen-2-yl)acetic Acid and Its Transformation into Perfluorinated 2-Methylnaphthalene and 6-Methyl-1,4-dihydronaphthalene Full article
| Journal |
Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2017, Volume: 53, Number: 12, Pages: 1822-1827 Pages count : 6 DOI: 10.1134/S1070428017120065 | ||||
| Authors |
|
||||
| Affiliations |
|
Abstract:
2,3-Dichlorodecafluorotetralin reacted with ethyl cyanoacetate to give ethyl 2-cyano-2-(6,7-dichlorononafluoro-5,6,7,8-tetrahydronaphthalen-2-yl) acetate which was hydrolyzed to (6,7-dichlorononafluoro5,6,7,8-tetrahydronaphthalen-2-yl) acetic acid. The latter was treated with PCl5 on heating to obtain 2,2-dichloro-(6,7-dichlorononafluoro-5,6,7,8-tetrahydronaphthalen-2-yl) acetyl chloride which was converted to 2,3-dichlorononafluoro-6-trifluoromethyl-1,2,3,4-tetrahydronaphthalene by the action of SbF5. The reduction of 2,3-dichlorononafluoro-6-trifluoromethyl-1,2,3,4-tetrahydronaphthalene with zinc in 1,4-dioxane gave perfluoro- 6-methyl-1,4-dihydronaphthalene, and in DMF, perfluoro-2-methylnaphthalene.
Cite:
Sinyakov V.R.
, Mezhenkova T.V.
, Karpov V.M.
, Zonov Y.V.
Synthesis of (6,7-Dichlorononafluoro-5,6,7,8-tetrahydronaphthalen-2-yl)acetic Acid and Its Transformation into Perfluorinated 2-Methylnaphthalene and 6-Methyl-1,4-dihydronaphthalene
Russian Journal of Organic Chemistry. 2017. V.53. N12. P.1822-1827. DOI: 10.1134/S1070428017120065 WOS Scopus РИНЦ OpenAlex
Synthesis of (6,7-Dichlorononafluoro-5,6,7,8-tetrahydronaphthalen-2-yl)acetic Acid and Its Transformation into Perfluorinated 2-Methylnaphthalene and 6-Methyl-1,4-dihydronaphthalene
Russian Journal of Organic Chemistry. 2017. V.53. N12. P.1822-1827. DOI: 10.1134/S1070428017120065 WOS Scopus РИНЦ OpenAlex
Original:
Синяков В.Р.
, Меженкова Т.В.
, Карпов В.М.
, Зонов Я.В.
Образование (6,7-дихлорперфтор-5,6,7,8-тетрагидронафталин-2-ил)- уксусной кислоты и синтез на её основе перфтор-2-метил- нафталина и перфтор-6-метил-1,4-дигидронафталина
Журнал органической химии (RUSS J ORG CHEM+). 2017. Т.53. №12. С.1786-1791. РИНЦ
Образование (6,7-дихлорперфтор-5,6,7,8-тетрагидронафталин-2-ил)- уксусной кислоты и синтез на её основе перфтор-2-метил- нафталина и перфтор-6-метил-1,4-дигидронафталина
Журнал органической химии (RUSS J ORG CHEM+). 2017. Т.53. №12. С.1786-1791. РИНЦ
Dates:
| Published print: | Dec 1, 2017 |
| Published online: | Jan 25, 2018 |
Identifiers:
| Web of science: | WOS:000423262100006 |
| Scopus: | 2-s2.0-85040996527 |
| Elibrary: | 35507342 |
| OpenAlex: | W2788337807 |