Thermolytic reactions of polyfluoroaromatic compounds-XI. Copyrolysis of pentafluorosubstituted derivatives of benzene with sources of difluorocarbene. Formation of perfluoroindan Full article
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Tetrahedron
ISSN: 0040-4020 |
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| Output data | Year: 1975, Volume: 31, Number: 9, Pages: 1201-1207 Pages count : DOI: 10.1016/0040-4020(75)85057-5 | ||
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Abstract:
Copyrolysis of compounds of the type C6F5X (X OH, OCH3, SH, NH2) with sources of difluorocarbene (CF2 CF2, CHClF2 and others) in a flow system at 600-700° is shown to give perfluoroindan in high yield. Perfluorinated methylindanes, perfluorocoumaran and other compounds are also formed. From pentafluorophenol and hexafluoropropylene oxide at 250° α,α,2,3,4,5,6-heptafluoroanisole is obtained. The participation of the perfluorobenzyl radical in the formation of perfluoroindan is discussed in the reactions investigated. © 1975.
Cite:
Malyuta N.G.
, Platonov V.E.
, Furin G.G.
, Yakobson G.G.
Thermolytic reactions of polyfluoroaromatic compounds-XI. Copyrolysis of pentafluorosubstituted derivatives of benzene with sources of difluorocarbene. Formation of perfluoroindan
Tetrahedron. 1975. V.31. N9. P.1201-1207. DOI: 10.1016/0040-4020(75)85057-5 WOS Scopus OpenAlex
Thermolytic reactions of polyfluoroaromatic compounds-XI. Copyrolysis of pentafluorosubstituted derivatives of benzene with sources of difluorocarbene. Formation of perfluoroindan
Tetrahedron. 1975. V.31. N9. P.1201-1207. DOI: 10.1016/0040-4020(75)85057-5 WOS Scopus OpenAlex
Dates:
| Published print: | Jan 1, 1975 |
Identifiers:
| Web of science: | WOS:A1975AA89100013 |
| Scopus: | 2-s2.0-0010773904 |
| OpenAlex: | W1551045661 |