Special features of polymerization of some perfluorinated aromatic and alicyclic compounds in glow discharge

Special features of polymerization of some perfluorinated aromatic and alicyclic compounds in glow discharge Full article

Journal

Polymer Science U.S.S.R.
ISSN: 0032-3950

Output data

Year: 1984, Volume: 26, Number: 7, Pages: 1709-1715 Pages count : 7 DOI: 10.1016/S0032-3950(84)80062-3

Authors

Gil'man A.B. ¹ , Shifrina R.R. ¹ , Platonov V.Ye. ² , Dvornikova K.V. ² , Kolotyrkin V.M. ¹ , Potapov V.K. ¹ , Yakobson G.G. ²

Affiliations

1	L. Ya. Karpov Scientific Research Institute of Physico-chemistry
2	Novosibirsk Institute of Organic Chemistry, U.S.S.R. Academy of Sciences, Russian Federation

A study was made of polymerization in glow discharge plasma of some perfluorinated compounds: perfluorobenzocyclobutene, perfluorindane, perfluorotetralin, perfluor-o-xylene, perfluoromesitylene, perfluorocyclopentene, perfluorocyclohexene and perfluorodecalin. Kinetics of formation of polymers, their elemental composition and IR spectra were examined. It was shown that an increase in the rate of formation of polymer films from perfluoraromatic compounds is due to processes, during which the breakdown of fluoraromatic rings is minimal, of nuclear condensation involving aliphatic chain segments. These segments are formed both during the rupture of aromatic rings and during the transformation of substituents (in the case of substituted compounds). © 1985 Pergamon Press Limited.

Gil'man A.B. , Shifrina R.R. , Platonov V.Y. , Dvornikova K.V. , Kolotyrkin V.M. , Potapov V.K. , Yakobson G.G.
Special features of polymerization of some perfluorinated aromatic and alicyclic compounds in glow discharge
Polymer Science U.S.S.R.. 1984. V.26. N7. P.1709-1715. DOI: 10.1016/S0032-3950(84)80062-3 Scopus OpenAlex

Published print:

Jan 1, 1984

Scopus:	2-s2.0-0021693810
OpenAlex:	W2020656731

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