Phase-transfer catalysis in electrophilic substitution reactions: VIII. Nitration of arenes with sodium nitrite in acid medium under conditions of phase-transfer catalysis

Phase-transfer catalysis in electrophilic substitution reactions: VIII. Nitration of arenes with sodium nitrite in acid medium under conditions of phase-transfer catalysis Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 1999, Volume: 35, Number: 7, Pages: 1039-1043 Pages count : 5

Authors

Zaraiskii A.P. ¹ , Kachurin O.I. ¹ , Velichko L.I. ¹ , Shur V.B. ² , Tikhonova I.A. ² , Furin G.G. ³

Affiliations

1	(Scopus) Litvinenko Inst. of Phys. Organ./C., Ukrainian Natl. Academy of Sciences, ul. R. Luxemburg 70, Donetsk, 340114, Ukraine
2	(Scopus) Nesmeyanov Inst. of O., Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russian Federation
3	(Scopus) Novosibirsk Inst. of Organ. Chem., Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russian Federation

Nitration of aromatic compounds with nitrous acid was studied under conditions of phase-transfer catalysis. Nitroarenes are formed in the system benzene-aqueous sulfuric acid by the electrophilic mechanism of phase-transfer catalysis. Noncatalytic process sometimes does not occur. The stoichiometry of the reaction depends on the amount of atmospheric oxygen in a closed system.

Zaraiskii A.P. , Kachurin O.I. , Velichko L.I. , Shur V.B. , Tikhonova I.A. , Furin G.G.
Phase-transfer catalysis in electrophilic substitution reactions: VIII. Nitration of arenes with sodium nitrite in acid medium under conditions of phase-transfer catalysis
Russian Journal of Organic Chemistry. 1999. V.35. N7. P.1039-1043. Scopus РИНЦ

Scopus:	2-s2.0-0033236279
Elibrary:	13326096

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