Modification of the Tiemann rearrangement: One-pot synthesis of N,N-disubstituted cyanamides from amidoximes

Journal

Synthesis
ISSN: 0039-7881

Output data

Year: 2000, Number: 8, Pages: 1148-1159 Pages count : 12 DOI: 10.1055/s-2000-6317

Tags

Alkylations; Amidoximes; Cyanamides; Phase-transfer catalysis; Tiemann rearrangement

Authors

Bakunov S.A. ¹ , Rukavishnikov A.V. ² , Tkachev A.V. ^1,2

Affiliations

1	(Scopus) Novosibirsk State University, Novosibirsk 630090, Russian Federation
2	(Scopus) Novosibirsk Inst. of Organ. Chem., Novosibirsk 630090, Russian Federation

A three-stage one-pot synthetic procedure for transformation of amidoximes to N,N-disubstituted cyanamides in 70-92% yield is described.

Bakunov S.A. , Rukavishnikov A.V. , Tkachev A.V.
Modification of the Tiemann rearrangement: One-pot synthesis of N,N-disubstituted cyanamides from amidoximes
Synthesis. 2000. N8. P.1148-1159. DOI: 10.1055/s-2000-6317 WOS Scopus РИНЦ OpenAlex