Reaction of anthrone and its 1- and 4-substituted derivatives with sulfur in the presence of nucleophiles

Reaction of anthrone and its 1- and 4-substituted derivatives with sulfur in the presence of nucleophiles Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2000, Volume: 36, Number: 10, Pages: 1478-1481 Pages count : 4

Authors

Loskutov V.A. ¹

Affiliations

1	(Scopus) Vorozhtsov Novosibirsk Inst. of O., Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russian Federation

Anthrone and its 1-substituted derivatives react with molecular sulfur in the presence of nucleophiles (aromatic amines, hydrazine, substituted hydrazines, and malononitrile) to give intermediate monothioanthraquinones which are then converted into mixtures of the corresponding anthraquinones and 10-imino-, 10-hydrazono-, or 10-dicyanomethylene-9,10-dihydroanthracen-9-ones. Unlike 1-substituted derivatives, 4-substituted anthrones react with sulfur in the presence of phenylhydrazine to give only 1-substituted anthraquinones.

Loskutov V.A.
Reaction of anthrone and its 1- and 4-substituted derivatives with sulfur in the presence of nucleophiles
Russian Journal of Organic Chemistry. 2000. V.36. N10. P.1478-1481. WOS Scopus РИНЦ

Web of science:	WOS:000168062000010
Scopus:	2-s2.0-0034287306
Elibrary:	13352493

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