Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines

Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2000, Volume: 10, Number: 1, Pages: 5-7 Pages count : 3 DOI: 10.1070/mc2000v010n01abeh001198

Authors

Bagryansky V.A. ¹ , Vlasyuk I.V. ² , Gatilov Y.V. ³ , Makarov A.Yu. ³ , Molin Y.N. ¹ , Shcherbukhin V.V. ⁴ , Zibarev A.V. ³

Affiliations

1	Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences 630090 Novosibirsk, Russian Federation
4	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow, Russian Federation

Mild thermolysis (at 110-150 °C) of 1,3,2,4-benzodithiadiazine 1 and its derivatives 2-6 in hydrocarbon solvents quantitatively yielded stable 1,2,3-benzodithiazolyl π-radicals via a first-order reaction (Ea = 76.2 kJ mol-1, k0 = 4.34×105 s-1 for 1).

Bagryansky V.A. , Vlasyuk I.V. , Gatilov Y.V. , Makarov A.Y. , Molin Y.N. , Shcherbukhin V.V. , Zibarev A.V.
Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines
Mendeleev Communications. 2000. V.10. N1. P.5-7. DOI: 10.1070/mc2000v010n01abeh001198 WOS Scopus РИНЦ OpenAlex

Published print:

Jan 1, 2000

Web of science:	WOS:000085384000003
Scopus:	2-s2.0-0038957503
Elibrary:	13335692
OpenAlex:	W1967698021

DB	Citing
Scopus	21
Web of science	19
Elibrary	26
OpenAlex	17