Sciact
  • EN
  • RU

The first hydrogen containing (polyfluorocycloalken-1-yl)xenon(II) salts Full article

Journal Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
ISSN: 0932-0776
Output data Year: 1998, Volume: 53, Number: 5-6, Pages: 562-564 Pages count : 3 DOI: 10.1515/znb-1998-5-612
Tags Fluorinated Alkenylxenon(II) Salts; Fluorinated Arylxenon(II) Salts; Oxidative Fluorination; Xenon Difluoride
Authors Frohr H.-J. 1 , Bardin V.V. 2
Affiliations
1 Fachgebiet Anorganische Chemie, Gerhard-Mercator-Univ. Duisburg, Lotharstr. 1, D-47048 Duisburg, Germany
2 Institute of Organic Chemistry, Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Abstract: (2-H-Hexafluoro-1,4-cyclohexadien-1-yl)xenon(II) and (2-H-octafluorocyclohexen-1-yl)xenon(II) hexafluoroarsenates and tetrafluoroborates were obtained together with their perfluorinated analogues on reacting the corresponding (2,3,4,5-tetrarluorophenyl)xenon(II) salts with XeF2 in anhydrous HF (aHF). The fluorinated (cyclohexen-1-yl)xenon(II) cations react with bromide and iodide anions in MeCN and aHF under alkenylation of the halide anions.
Cite: Frohr H.-J. , Bardin V.V.
The first hydrogen containing (polyfluorocycloalken-1-yl)xenon(II) salts
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1998. V.53. N5-6. P.562-564. DOI: 10.1515/znb-1998-5-612 WOS Scopus OpenAlex
Dates:
Published print: Jun 1, 1998
Published online: Jun 2, 2014
Identifiers:
Web of science: WOS:000074694700012
Scopus: 2-s2.0-0040583605
OpenAlex: W1988211377
Citing:
DB Citing
Scopus 9
Web of science 7
OpenAlex 5
Altmetrics: