A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates Full article
| Journal |
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
ISSN: 0932-0776 |
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| Output data | Year: 1999, Volume: 54, Number: 12, Pages: 1495-1498 Pages count : 4 DOI: 10.1515/znb-1999-1203 | ||||
| Tags | Fluorinated Aryldifluoroboranes; Fluorinated Arylxenon(II) Salts; Fluorine-Aryl Substitution; Thermal Decomposition; Xenon Difluoride | ||||
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Abstract:
An improved synthesis of arylxenon(II) salts is reported. The series of fluoro-containing arylxenon(II) tetrafluoroborates (aryl = C6F5, 2,3,4,5-C6HF4, 3,4,5-C6H2F3 and 3,5-C6H3F2) are prepared by the reaction of xenon difluoride with the corresponding aryldifluoroboranes. The salts [C6F5Xe] [BF4] and [2,3,4,5-C6HF4Xe] [BF4] are long-term stable in anhydrous HF (aHF) solution at rt, while [3,4,5-C6H2F3Xe] [BF4] and [3,5-C6H3F2Xe] [BF4] are converted into 1,2,3,5-tetrafluorobenzene and 1,3,5-trifluorobenzene, respectively, within a few hours.
Cite:
Frohn H.-J.
, Franke H.
, Bardin V.V.
A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1999. V.54. N12. P.1495-1498. DOI: 10.1515/znb-1999-1203 WOS Scopus РИНЦ OpenAlex
A Simple and Convenient Route to Arylxenon(II) Tetrafluoroborates
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1999. V.54. N12. P.1495-1498. DOI: 10.1515/znb-1999-1203 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Dec 1, 1999 |
| Published online: | Jun 2, 2014 |
Identifiers:
| Web of science: | WOS:000084904600003 |
| Scopus: | 2-s2.0-0042542855 |
| Elibrary: | 13315953 |
| OpenAlex: | W2321367133 |