Alkylation of Enaminoketone with a Modified Carane Skeleton. Formation of Stable β-Diketone Monoimines

Alkylation of Enaminoketone with a Modified Carane Skeleton. Formation of Stable β-Diketone Monoimines Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 1997, Том: 33, Номер: 5, Страницы: 601-606 Страниц : 6

Авторы

Tkachev A.V. ¹ , Popov S.A. ¹

Организации

1	(Scopus) Novosibirsk Inst. of Organ. Chem., Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russian Federation

Alkylation of a bicyclic enaminoketone, 1-[(1R,5R)-3-amino-6,6-dimethylbicyclo[3.1.0]hex-2-en-2-yl)]ethanone, with highly reactive alkyl halides (methyl iodide, benzyl halides, and allyl halides) in a two-phase system benzene-40% aqueous NaOH in the presence of benzyltriethylammonium chloride (BTEA) as phase-transfer catalyst results in formation of stable β-diketone monoimines, derivatives of the series of 1-[(1R,5R)-2-alkyl-3-imino-6,6-dimethylbicyclo[3.1.0]hex-2-yl]ethanone, in 53-81% yields.

Tkachev A.V. , Popov S.A.
Alkylation of Enaminoketone with a Modified Carane Skeleton. Formation of Stable β-Diketone Monoimines
Russian Journal of Organic Chemistry. 1997. V.33. N5. P.601-606. Scopus РИНЦ

Tkachev A.V. , Popov S.A.
Alkylation of enaminoketone with modified carane skeleton. Formation of beta-diketone stable monoimines
Журнал органической химии (RUSS J ORG CHEM+). 1997. V.33. N5. P.660-665. WOS

Scopus:	2-s2.0-0347107769
РИНЦ:	13261524

БД	Цитирований
РИНЦ	2