1H and 13C NMR study of azido-tetrazole tautomerism of 2-azido-4-methylpyrimidine

1H and 13C NMR study of azido-tetrazole tautomerism of 2-azido-4-methylpyrimidine Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Output data

Year: 1990, Volume: 26, Number: 12, Pages: 1370-1375 Pages count : DOI: 10.1007/BF00473966

Authors

Krivopoalov V. P. , Mamatyuk V. O. , Mamaev V. P.

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk, 630090, Russian Federation

Using 1H and 13C NMR and IR spectroscopic methods, it was found that 2-azido-4-methylpyrimidine exists in solutions in tautomeric equilibrium with two tetrazole forms, the ratio between which is determined by the polarity of the solvent, while in a crystalline state, according to the 13C NMR CP MAS data it has the structure of the 7-methyltetrazolo[1,5-a]pyrimidine isomer. © 1991 Plenum Publishing Corporation.

Krivopoalov V.P. , Mamatyuk V.O. , Mamaev V.P.
1H and 13C NMR study of azido-tetrazole tautomerism of 2-azido-4-methylpyrimidine
Chemistry of Heterocyclic Compounds. 1990. V.26. N12. P.1370-1375. DOI: 10.1007/BF00473966 Scopus РИНЦ OpenAlex

Published print:

Dec 1, 1990

Scopus:	2-s2.0-34249916972
Elibrary:	30832285
OpenAlex:	W1983561546

DB	Citing
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Elibrary	3
OpenAlex	6