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Additive character of the resonance constants of azinyl groups Full article

Journal Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353
Output data Year: 1989, Volume: 25, Number: 3, Pages: 296-300 Pages count : DOI: 10.1007/BF00472389
Authors Shkurko O. P. , Mamaev V. P.
Affiliations
1 (Scopus) Novosibirsk Institute of Organic Chemistry Siberian Branch, Academy of Sciences of the USSR, Novosibirsk, 630090, Russian Federation

Abstract: The increments for the endocyclic nitrogen atoms in various positions of the azine ring, which make it possible to calculate the resonance constants of azinyl groups via an additive scheme, were found. A correlation between the resonance constants and the π-electron charges in the corresponding ipso positions of the azine ring was noted. Correlated constants of the Hammett type, which quantitatively describe the CH acidities of methyl azines and the NH acidities of amino azines were derived. © 1989 Plenum Publishing Corporation.
Cite: Shkurko O.P. , Mamaev V.P.
Additive character of the resonance constants of azinyl groups
Chemistry of Heterocyclic Compounds. 1989. V.25. N3. P.296-300. DOI: 10.1007/BF00472389 Scopus РИНЦ OpenAlex
Dates:
Published print: Mar 1, 1989
Identifiers:
Scopus: 2-s2.0-34249971603
Elibrary: 30988292
OpenAlex: W2040753790
Citing: Пока нет цитирований
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