The nature of the inductive effect of azinyl groups Full article
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Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353 |
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| Output data | Year: 1987, Volume: 23, Number: 5, Pages: 558-562 Pages count : DOI: 10.1007/BF00476388 | ||
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Abstract:
The induction constants of azinyl groups are factored into two components, a σ-induction (σX) and a field (σF) component. It is shown that the σX constants of azinyl groups can be thought of as sums of contributions from the phenyl group and the endocyclic nitrogen atoms. A satisfactory correlation is found between the σF constants and the size and direction of the dipole moment of the heterocyclic substituents in the framework of the Kirkwood-Westheimer equation. © 1987 Plenum Publishing Corporation.
Cite:
Shkurko O.P.
, Mamaev V.P.
The nature of the inductive effect of azinyl groups
Chemistry of Heterocyclic Compounds. 1987. V.23. N5. P.558-562. DOI: 10.1007/BF00476388 Scopus РИНЦ OpenAlex
The nature of the inductive effect of azinyl groups
Chemistry of Heterocyclic Compounds. 1987. V.23. N5. P.558-562. DOI: 10.1007/BF00476388 Scopus РИНЦ OpenAlex
Dates:
| Published print: | May 1, 1987 |
Identifiers:
| Scopus: | 2-s2.0-34250105219 |
| Elibrary: | 30892283 |
| OpenAlex: | W2008977943 |