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Tautomerism of azine derivatives. 7. Thermodynamic parameters of the 1,3-prototropic tautomeric equilibrium of azahetarylmethanes Научная публикация

Журнал Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353
Вых. Данные Год: 1984, Том: 20, Номер: 6, Страницы: 680-683 Страниц : DOI: 10.1007/BF00508684
Авторы Petrenko O. P. , Bychkov S. F. , Lapachev V. V. , Mamaev V. P.
Организации
1 (Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk, 630090, Russian Federation

Реферат: The constants of the hetaryl-ylidene tautomeric equilibrium in CDCl3 over a wide range of temperatures were measured for azinylmalonic and azinylcyanoacetic acid esters. High-temperature sensitivity of the position of the equilibrium for 2-pyrimidinylcyanoacetic acid esters was demonstrated. The differences in the δS values of the equilibrium for derivatives of malonic and cyanoacetic acid esters were explained by different freedoms of rotation about the exocyclic C-C bond in the aromatic tautomeric form. © 1984 Plenum Publishing Corporation.
Библиографическая ссылка: Petrenko O.P. , Bychkov S.F. , Lapachev V.V. , Mamaev V.P.
Tautomerism of azine derivatives. 7. Thermodynamic parameters of the 1,3-prototropic tautomeric equilibrium of azahetarylmethanes
Chemistry of Heterocyclic Compounds. 1984. V.20. N6. P.680-683. DOI: 10.1007/BF00508684 Scopus РИНЦ OpenAlex
Даты:
Опубликована в печати: 1 июн. 1984 г.
Идентификаторы БД:
Scopus: 2-s2.0-34250140866
РИНЦ: 30915570
OpenAlex: W2950487888
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