Anion radicals in the reaction of substituted 2,6-dinitroanisoles with potassium methoxide

Anion radicals in the reaction of substituted 2,6-dinitroanisoles with potassium methoxide Full article

Journal

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230

Output data

Year: 1976, Volume: 25, Number: 4, Pages: 755-761 Pages count : 7 DOI: 10.1007/BF00922374

Authors

Starichenko V.F. ¹ , Ryabinin V.A. ¹ , Shein S.M. ¹

Affiliations

1	(Scopus) Siberian Branch, Novosibirsk Institute of Organic Chemistry of the Academy of Sciences of the USSR, Russia

1. The reaction of 2,6-dinitro-4R-anisoles (R=OCH3, Cl, H, COO-) with potassium methoxide has been found to result in the formation of the anion radicals of these compounds; the anion radicals of the anionic σ complexes, i.e., the potassium 1,1-dimethoxy-3,6-dinitro-4R-cyclohexadienates (R=Cl, OCH3, H); the anion radicals of the 2-nitroso-4R-6-nitroanisoles (R=OCH3, Cl, H, COO-); and the anion radicals of the 2-nitroso-3-methoxy-4R-6-nitroanisoles (R=Cl, OCH3). 2. The structures have been established and mechanisms have been proposed for the formation of these anion radicals. © 1976 Plenum Publishing Corporation.

Starichenko V.F. , Ryabinin V.A. , Shein S.M.
Anion radicals in the reaction of substituted 2,6-dinitroanisoles with potassium methoxide
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1976. V.25. N4. P.755-761. DOI: 10.1007/BF00922374 WOS Scopus OpenAlex

Стариченко В.Ф. , Рябинин В.А. , Шейн С.М.
Анион-радикалы в реакции замещенных 2,6-динитроанизолов с метилатом калия
Известия Академии наук СССР. Серия химическая (с 1963 по 1992 год). 1976. №4. С.775-785. РИНЦ

Published print:

Apr 1, 1976

Web of science:	WOS:A1976CQ54100011
Scopus:	2-s2.0-34250302144
OpenAlex:	W2060665246

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