Reaction of N-(4-oxo-2-methyl-2-pentyl) -α-phenylnitrone with hydroxylamine

Reaction of N-(4-oxo-2-methyl-2-pentyl) -α-phenylnitrone with hydroxylamine Full article

Journal

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230

Output data

Year: 1973, Volume: 22, Number: 10, Pages: 2318-2319 Pages count : 2 DOI: 10.1007/BF01199647

Authors

Tikhonov A.Ya. ¹ , Volodarskii L.B. ¹

Affiliations

1	(Scopus) Siberian Branch of the Academy of Science of the USSR, Novosibirsk Institute of Organic Chemistry

1. The reaction of mesityl oxide with anti-benzaldoxime gives the N-alkylation product, namely N-(4-oxo-2-methyl-2-pentyl)-α-phenylnitrone; the reaction is reversible. 2. The treatment of N-(4-oxo-2-methyl-2-pentyl)-α-phenyl-nitrone with hydroxylamine gives N-(4-hydroxyimino-2-methyl-2-pentyl)hydroxylamine and 5-hydroxy-3,3,5-trimethylisoxazolidine. The latter is the intermolecular cyclization product of the intermediate β-hydroxylamine ketone. © 1974 Consultants Bureau.

Tikhonov A.Y. , Volodarskii L.B.
Reaction of N-(4-oxo-2-methyl-2-pentyl) -α-phenylnitrone with hydroxylamine
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1973. V.22. N10. P.2318-2319. DOI: 10.1007/BF01199647 Scopus РИНЦ OpenAlex

Published print:

Oct 1, 1973

Scopus:	2-s2.0-34250438374
Elibrary:	30980952
OpenAlex:	W2086764706

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