Investigation of the products of reaction of epichlorohydrin with aromatic amines - II. N-(γ-chloro-β-hydroxypropyl)diphenylamine and its reaction products Full article
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Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353 |
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| Output data | Year: 1966, Volume: 1, Number: 4, Pages: 368-371 Pages count : 4 DOI: 10.1007/BF00473811 | ||
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Abstract:
Epichlorohydrin reacts with diphenylamine in the presence of acetic acid to give N-(γ-chloro-β-hydroxypropyl)diphenylamine, cyclized to N-phenyl-1, 2, 3, 4-tetrahydro-3-hydroxyquinoline; a study is also made of its conversion to N-(γ-diphenylamine-β-hydroxypropyl)pyridinium chloride, N-(γ-amino-β-hydroxypropyl)diphenylamine, (γ-diphenylamino-β-hydroxybutyronitrile, and N-(β, γ-epoxypropyl)diphenylamine, the latter on treatment with hydrogen chloride giving back the starting N-(γ-chloro-β-hydroxypropyldiphenylamine. It is shown that when γ-diphenylamino-β-hydroxybutyronitrile is heated in alkali, the products are the salt of γ-diphenylamino-β-hydroxybutyric acid and diphenylamine, i.e. a nitrogen-carbon bond is broken. © 1966 The Faraday Press, Inc.
Cite:
Kutkevichus S.I.
, Vorozhtsov N.N.
Investigation of the products of reaction of epichlorohydrin with aromatic amines - II. N-(γ-chloro-β-hydroxypropyl)diphenylamine and its reaction products
Chemistry of Heterocyclic Compounds. 1966. V.1. N4. P.368-371. DOI: 10.1007/BF00473811 Scopus РИНЦ OpenAlex
Investigation of the products of reaction of epichlorohydrin with aromatic amines - II. N-(γ-chloro-β-hydroxypropyl)diphenylamine and its reaction products
Chemistry of Heterocyclic Compounds. 1966. V.1. N4. P.368-371. DOI: 10.1007/BF00473811 Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jul 1, 1966 |
Identifiers:
| ≡ Scopus: | 2-s2.0-34250538031 |
| ≡ Elibrary: | 30872919 |
| ≡ OpenAlex: | W3007982247 |