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Intramolecular Cyclization in 4-Azido-5-ethoxycarbonyl-2-(2′-hydroxyphenyOpyrimidine: Synthesis and Properties of 3-Ethoxy-6-(2′-hydroxyphenyl)isoxazolo[3,4-d]pyrimidine Full article

Journal Mendeleev Communications
ISSN: 0959-9436
Output data Year: 1993, Volume: 3, Number: 4, Pages: 151-153 Pages count : 3 DOI: 10.1070/MC1993v003n04ABEH000263
Authors Vetchinov V.P. 1 , Nikolaenkova E.B. 1 , Mamatyuk V.I. 1 , Krivopalov V.P. 1
Affiliations
1 (Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Abstract: The title azide in the solid state or in DMSO solution cyclizes thermally to isoxazolo[3,4-d]pyrimidine 2, which can either further rearrange to isoxazolone 3 or be transformed to hydroxylamine 5 or sulfoximine 7 on interaction with water or upon dilution of its DMSO solution by water, respectively; the tetrazolo tautomer 1T yields the acrylate 6. © 1993, jointly by The Russian Academy of Sciences and The Royal Society of Chemistry (Turpion Ltd). All rights reserved.
Cite: Vetchinov V.P. , Nikolaenkova E.B. , Mamatyuk V.I. , Krivopalov V.P.
Intramolecular Cyclization in 4-Azido-5-ethoxycarbonyl-2-(2′-hydroxyphenyOpyrimidine: Synthesis and Properties of 3-Ethoxy-6-(2′-hydroxyphenyl)isoxazolo[3,4-d]pyrimidine
Mendeleev Communications. 1993. V.3. N4. P.151-153. DOI: 10.1070/MC1993v003n04ABEH000263 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Jan 1, 1993
Identifiers:
Web of science: WOS:A1993LZ95000010
Scopus: 2-s2.0-4243399937
Elibrary: 30904401
OpenAlex: W2043494018
Citing:
DB Citing
Scopus 5
Web of science 4
Elibrary 4
OpenAlex 4
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