Реферат: Treatment of some 1,3-diaryl-2-chloropropane-1,3-diones, acyclic chloro-substituted enaminones and β-oxo esters with nucleophiles was shown to proceed easily with the formation, at least in the first stage, of formal nucleophilic substitution products. Treatment of enaminones and β-oxo esters with azide and cyanide ions proceeds with the preservation of the skeleton, whereas chloro-substituted diaroylmethanes undergo retro-Claisen-Claisen condensation reactions in the course of the reaction with cyanide. Dibenzoylchloromethane reacts with azide and cyanide ions with fragmentation of the molecule and subsequent reassembly, resulting in benzoylated benzaldehyde cyanohydrin and a 1,3-oxathiol derivative, respectively. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Библиографическая ссылка: Roshchupkina G.I. , Gatilov Y.V. , Rybalova T.V. , Reznikov V.A.
Reactions of 1,3-diaryl-2-chloropropane-1,3-diones with nucleophiles - Cyanide-induced retro-Claisen-Claisen condensation
European Journal of Organic Chemistry. 2004. N8. P.1765-1773. DOI: 10.1002/ejoc.200300739 WOS Scopus РИНЦ OpenAlex

Даты:

Опубликована в печати:

1 апр. 2004 г.

Идентификаторы БД:

Web of science:	WOS:000221027500014
Scopus:	2-s2.0-4544219752
РИНЦ:	13463167
OpenAlex:	W2031765874

Цитирование в БД:

БД	Цитирований
Scopus	17
Web of science	17
РИНЦ	17
OpenAlex	14

Альметрики: