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Arene transition metal complexes in reactions with nucleophilic agents. XII. The synthesis of a series of bis(arene)chromium complexes with a varied substituent in one of the ligands Научная публикация

Журнал Journal of Organometallic Chemistry
ISSN: 0022-328X
Вых. Данные Год: 1986, Том: 310, Номер: 2, Страницы: 189-201 Страниц : 13 DOI: 10.1016/S0022-328X(00)99552-4
Авторы Litvak V.V. 1 , Kun P.P. 1 , Oleynik I.I. 1 , Volkov O.V. 1 , Shteingarts V.D. 1
Организации
1 Institute of Organic Chemistry, Siberian Division of the USSR Academy of Sciences, Novosibirsk, 630090, Ave. Laurent'ev, 9 (U.S.S.R.) and Novosibirsk State Unuverdity, Novosibirsk, 630090, Pirogova Str., 2 U.S.S.R.

Реферат: An approach to the synthesis of a series of bis(arene)chromium complexes with a varied substituent in one of the ligands has been worked out, which involves low-temperature co-condensation of chromium vapours with arenes followed by the modification of substituents in arene ligands. In this way a series of complexes have been obtained: (η-C6H5Cl)(η-C6H5X)C r+A- (X = H, NMe2, {A figure is presented}, {A figure is presented}, {A figure is presented} OMe, OEt, OPr-i, OBu-N, Cl, CO2H, CO2Me, CF3); (η-C6H6)- (η-XC6H4Cl)Cr+A- (X = H, P-NMe2, p-OMe, m-OMe, p-Me, m-Me, p-Cl, m-Cl, p-CO2Me, m-CO2Me, p-CO2H, m-CO2H, (A- = PF6-, BPh4-); (η-C6H5X)(η-C6H5CO 2H)Cr+PF6- (X = H, OPr-i, OBu-n, OMe, Me, Cl, CO2H, CO2Me, CF3); (η-C6H6)(η-XC6H4CO 2H)Cr+PF6- (X = H, p-OMe, m-OMe, p-Me, p-Cl, m-Cl, p-CO2H, p-CO2Me); (η-C6H5CO2H)(η-C6 H5X)Cr (X = H, Cl, CF3, CO2Me, CO2H, OMe). © 1986.
Библиографическая ссылка: Litvak V.V. , Kun P.P. , Oleynik I.I. , Volkov O.V. , Shteingarts V.D.
Arene transition metal complexes in reactions with nucleophilic agents. XII. The synthesis of a series of bis(arene)chromium complexes with a varied substituent in one of the ligands
Journal of Organometallic Chemistry. 1986. V.310. N2. P.189-201. DOI: 10.1016/S0022-328X(00)99552-4 WOS Scopus OpenAlex
Даты:
Опубликована в печати: 1 авг. 1986 г.
Идентификаторы БД:
Web of science: WOS:A1986D720400006
Scopus: 2-s2.0-50849149037
OpenAlex: W1581444768
Цитирование в БД:
БД Цитирований
Scopus 4
Web of science 5
OpenAlex 7
Альметрики: