Zinc(II) Hexafluoroacetylacetonate Complexes of Alkoxyamines: NMR and Kinetic Investigations. First Step for a New Way to Prepare Hybrid Materials Full article
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ChemistrySelect
ISSN: 2365-6549 |
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| Output data | Year: 2017, Volume: 2, Number: 12, Pages: 3584-3593 Pages count : 10 DOI: 10.1002/slct.201700678 | ||||||
| Tags | activation; alkoxyamines; C-ON bond homolysis; rate enhancement; Zn(hfac)(2) complexes | ||||||
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Abstract:
A series of Zn(hfac)(2) alkoxyamines (diethyl(2,2-dimethyl-1-(tert-butyl-(1-pyridylethoxy)amino)propyl)phosphonate) coordinated at ortho, meta and para positions of their pyridyl moiety were prepared and their homolysis rate constants k(d) measured. Up to a 30-fold increase in k(d) was observed for the meta-(Zn-RR/SS) and para-(Zn-RR/SS) regioisomers. Moreover, the activation is also controlled by the amount of pyridine, used as a ligand competitor. XRD, H-1 and P-31 NMR spectra show very different structures for each complexes in solid state and in solution depending on the diastereosiomers and on the regioisomers.
Cite:
Audran G.
, Bagryanskaya E.
, Bagryanskaya I.
, Edeleva M.
, Marque S.R.A.
, Parkhomenko D.
, Tretyakov E.
, Zhivetyeva S.
Zinc(II) Hexafluoroacetylacetonate Complexes of Alkoxyamines: NMR and Kinetic Investigations. First Step for a New Way to Prepare Hybrid Materials
ChemistrySelect. 2017. V.2. N12. P.3584-3593. DOI: 10.1002/slct.201700678 WOS Scopus РИНЦ OpenAlex
Zinc(II) Hexafluoroacetylacetonate Complexes of Alkoxyamines: NMR and Kinetic Investigations. First Step for a New Way to Prepare Hybrid Materials
ChemistrySelect. 2017. V.2. N12. P.3584-3593. DOI: 10.1002/slct.201700678 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Apr 24, 2017 |
| Published online: | Apr 27, 2017 |
Identifiers:
| Web of science: | WOS:000400379900028 |
| Scopus: | 2-s2.0-85020052552 |
| Elibrary: | 35508770 |
| OpenAlex: | W2607824840 |