Investigation of molecular carbonium ion rearrangements by the molecular mechanics method Full article
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Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Output data | Year: 1992, Volume: 61, Number: 11, Pages: 1077-1084 Pages count : 8 DOI: 10.1070/RC1992v061n11ABEH001017 | ||
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Abstract:
The review considers problems of the application of the molecular mechanics method in the prediction of the conversion reactions of hydrocarbon carbonium ions with a localised charge. The methods for the estimation of the heights of the activation barriers to the 1, 2-shift of the migrating species, the possibilities of the method for the prediction of the transannular cyclisation of carbonium ions, and certain examples of the influence of the acidity of the medium are discussed. © 1992 IOP Publishing Ltd.
Cite:
Gatilov Y.V.
, Barkhash V.A.
Investigation of molecular carbonium ion rearrangements by the molecular mechanics method
Russian Chemical Reviews. 1992. V.61. N11. P.1077-1084. DOI: 10.1070/RC1992v061n11ABEH001017 Scopus РИНЦ OpenAlex
Investigation of molecular carbonium ion rearrangements by the molecular mechanics method
Russian Chemical Reviews. 1992. V.61. N11. P.1077-1084. DOI: 10.1070/RC1992v061n11ABEH001017 Scopus РИНЦ OpenAlex
Dates:
| Published print: | Nov 30, 1992 |
| Published online: | Oct 17, 2007 |
Identifiers:
| Scopus: | 2-s2.0-84949839389 |
| Elibrary: | 32802491 |
| OpenAlex: | W2004677324 |