Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties Full article
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Polymer Science - Series B
ISSN: 1560-0904 |
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| Output data | Year: 2020, Volume: 62, Number: 5, Pages: 509-521 Pages count : 13 DOI: 10.1134/S1560090420050048 | ||||
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Abstract:
Abstract: A transparent hybrid photopolymer material is synthesized on the basis of (8-acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl acrylate and 3-[3-(3-mercaptopropyl)-1,1,3,5-tetramethoxy-5,5-diphenyltrisiloxane]propane-1-thiol. Using NMR spectroscopy and MALDI TOF mass spectrometry, the ability of the thiol-siloxane compound to undergo spontaneous hydrolytic condensation during storage is studied. The hybrid photopolymer films were obtained at different ratio of the components (from 16 : 1 to 1 : 2), and their thermomechanical and optical properties are investigated. The values of the storage modulus (0.9–2.3 GPa), the glass transition temperature (73–111°C), and the refractive index (1.56–1.59) are determined. On the basis of the 4 : 1 hybrid composition, a replica of relief microstructures with characteristic sizes of square elements of 5 × 0.8 μm is presented. © 2020, Pleiades Publishing, Ltd.
Cite:
Derevyanko D.I.
, Basistyi V.S.
, Shelkovnikov V.V.
, Shundrina I.K.
, Bukhtoyarova A.D.
, Sa?nikov G.E.
, Berezhnaya V.N.
, Chernonosov A.A.
Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties
Polymer Science - Series B. 2020. V.62. N5. P.509-521. DOI: 10.1134/S1560090420050048 WOS Scopus РИНЦ OpenAlex
Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties
Polymer Science - Series B. 2020. V.62. N5. P.509-521. DOI: 10.1134/S1560090420050048 WOS Scopus РИНЦ OpenAlex
Original:
Деревянко Д.И.
, Басистый В.С.
, Шелковников В.В.
, Шундрина И.К.
, Бухтоярова А.Д.
, Сальников Г.Е.
, Бережная В.Н.
, Черноносов А.А.
ГИБРИДНЫЙ ФОТОПОЛИМЕРНЫЙ МАТЕРИАЛ НА ОСНОВЕ (8-АКРИЛОИЛ-1,4-ДИТИА-8-АЗАСПИРО[4.5]ДЕКАН-2-ИЛ)МЕТИЛ АКРИЛАТА И ТИОЛ-СИЛОКСАНОВОГО КОМПОНЕНТА ДЛЯ ЗАПИСИ МИКРОСТРУКТУР: СИНТЕЗ, ОПТИЧЕСКИЕ И ТЕРМОМЕХАНИЧЕСКИЕ СВОЙСТВА
Высокомолекулярные соединения. Серия Б. 2020. Т.52. №5. С.382-394. DOI: 10.31857/S2308113920050046 РИНЦ OpenAlex
ГИБРИДНЫЙ ФОТОПОЛИМЕРНЫЙ МАТЕРИАЛ НА ОСНОВЕ (8-АКРИЛОИЛ-1,4-ДИТИА-8-АЗАСПИРО[4.5]ДЕКАН-2-ИЛ)МЕТИЛ АКРИЛАТА И ТИОЛ-СИЛОКСАНОВОГО КОМПОНЕНТА ДЛЯ ЗАПИСИ МИКРОСТРУКТУР: СИНТЕЗ, ОПТИЧЕСКИЕ И ТЕРМОМЕХАНИЧЕСКИЕ СВОЙСТВА
Высокомолекулярные соединения. Серия Б. 2020. Т.52. №5. С.382-394. DOI: 10.31857/S2308113920050046 РИНЦ OpenAlex
Dates:
| Published print: | Sep 1, 2020 |
| Published online: | Oct 30, 2020 |
Identifiers:
| Web of science: | WOS:000583051100009 |
| Scopus: | 2-s2.0-85092576310 |
| Elibrary: | 45228111 |
| OpenAlex: | W3096449152 |