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Synthesis, characterization and organic field-effect transistors applications of novel tetrathienoacene derivatives Full article

Journal Dyes and Pigments
ISSN: 0143-7208 , E-ISSN: 1873-3743
Output data Year: 2021, Volume: 185, Article number : 108911, Pages count : DOI: 10.1016/j.dyepig.2020.108911
Tags Absorption and luminescence spectra; electroluminescence; Organic semiconductors; Tetrathienothiophene; Оrganic field effect transistors
Authors Borshchev O.V. 1 , Skorotetcky M.S. 1 , Trukhanov V.A. 1,2 , Fedorenko Roman S. 1,2 , Surin N.M. 1 , Svidchenko Evgeniya A. 1 , Sosorev A.Y. 1,2 , Kazantsev M.S. 3,4 , Paraschuk D.Y. 1,2 , Ponomarenko S.A. 1
Affiliations
1 (Scopus) Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences, Profsoyuznaya St. 70, Moscow, 117393, Russian Federation
2 (Scopus) Faculty of Physics & International Laser Centre of Lomonosov Moscow State University, Leninskiye gory 1/62, Moscow, 119991, Russian Federation
3 (Scopus) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Lavrentieva 9, Novosibirsk, 630090, Russian Federation
4 (Scopus) Novosibirsk State University, Pirogova 2, Novosibirsk, 630090, Russian Federation

Abstract: Two novel organic semiconductors with tetrathienoacene (TTA) as the central core end-capped with 5-hexyl-2-thiophene, (Hex-T)2-TTA, and 4-hexyl-phenyl, (Hex-Ph)2-TTA, have been synthesized and investigated for organic field effect transistor (OFET) applications. The novel TTA derivatives were characterized by thermal gravimetric analysis, differential scanning calorimetry, UV–Vis spectroscopy, and cyclic voltammetry as well as studied by density functional theory calculations. Two types of OFETs with the solution and vacuum-deposited active layer were fabricated and characterized. Both TTA-derivatives demonstrated electroluminescence in OFETs, and (Hex-Ph)2-TTA showed ambipolar charge transport with the hole mobility as high as 0.68 cm2 V−1s−1. © 2020 Elsevier Ltd
Cite: Borshchev O.V. , Skorotetcky M.S. , Trukhanov V.A. , Fedorenko R.S. , Surin N.M. , Svidchenko E.A. , Sosorev A.Y. , Kazantsev M.S. , Paraschuk D.Y. , Ponomarenko S.A.
Synthesis, characterization and organic field-effect transistors applications of novel tetrathienoacene derivatives
Dyes and Pigments. 2021. V.185. 108911 . DOI: 10.1016/j.dyepig.2020.108911 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Feb 1, 2021
Identifiers:
Web of science: WOS:000600371800010
Scopus: 2-s2.0-85092732438
Elibrary: 45219840
OpenAlex: W3092430797
Citing:
DB Citing
Scopus 13
Web of science 13
Elibrary 14
OpenAlex 13
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