Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols

Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353

Output data

Year: 2020, Volume: 56, Number: 11, Pages: 1440-1448 Pages count : 9 DOI: 10.1007/s10593-020-02835-w

Tags

1-(tert-butyl)-4-(sec-butyl)-3-nitro-1,2,4-triazolium salt; 1-(sec-butyl)-3,5-dinitro-1H-1,2,4-triazole; N-(sec-butyl)-3(5)-nitro-1,2,4-triazole; alkylation; isomers; transformation of alkyl substituent; X-ray structural analysis

Authors

Sukhanov Gennady T. ¹ , Krupnova Irina A. ¹ , Filippova Yuliya ¹ , Gatilov Yurii ² , Sukhanova Anna G. ¹ , Bosov Konstantin K. ¹ , Pivovarova Ekaterina ¹

Affiliations

1	Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk, 659322, Russia
2	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk, 630090, Russia

The directions of thermodynamically controlled rearrangements and transformations of alkyl substituents under the conditions of acidcatalyzed alkylation of unsubstituted and 5(3)-substituted 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols (n-, i-, tert-, sec-BuOH) were studied.

Sukhanov G.T. , Krupnova I.A. , Filippova Y. , Gatilov Y. , Sukhanova A.G. , Bosov K.K. , Pivovarova E.
Synthesis and transformations of N-butyl-3(5)-nitro-1,2,4-triazoles under the conditions of acid-catalyzed alkylation of 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols
Chemistry of Heterocyclic Compounds. 2020. V.56. N11. P.1440-1448. DOI: 10.1007/s10593-020-02835-w WOS Scopus РИНЦ OpenAlex

Published print:	Nov 1, 2020
Published online:	Dec 3, 2020

Web of science:	WOS:000595754000010
Scopus:	2-s2.0-85097216980
Elibrary:	45098696
OpenAlex:	W3111972155

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