A COMPLEX OF Zn(II) WITH CHIRAL NOPINANE-ANNELATED 9,9 '-bi-4,5-DIAZAFLUORENYLIDENE: SYNTHESIS, STRUCTURE, AND PROPERTIES Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2020, Volume: 61, Number: 10, Pages: 1606-1614 Pages count : 9 DOI: 10.1134/S0022476620100133 | ||||
| Tags | terpenes; diazafluorenylidene; complex of Zn(II); structure; photoluminecence | ||||
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Abstract:
Complex ZnLCl2 center dot EtOH center dot H2O (I) where L is chiral 9,9 '-bi-4,5-diazafluorenylidene containing fragments of natural monoterpenoide (-)-alpha-pinene is synthesized. The crystal structure of I is composed of ZnLCl2 mononuclear complex, solvate EtOH, and H2O molecules. The coordination polyhedron Cl2N2 of the Zn atom is a distorted tetrahedron. L is a bidentate cyclic ligand, involving only two N atoms in the coordination. Complex I is characterized by IR and NMR spectroscopy and its thermal properties are analyzed. In the solid phase, L exhibits photoluminescence is the visible range (lambda(max) = 610 nm).
Cite:
Kokina T.E.
, Glinskaya L.A.
, Piryazev D.A.
, Vasiliev E.S.
, Sheludyakova L.A.
, Rakhmanova M.I.
, Tkachev A.V.
A COMPLEX OF Zn(II) WITH CHIRAL NOPINANE-ANNELATED 9,9 '-bi-4,5-DIAZAFLUORENYLIDENE: SYNTHESIS, STRUCTURE, AND PROPERTIES
Journal of Structural Chemistry. 2020. V.61. N10. P.1606-1614. DOI: 10.1134/S0022476620100133 WOS Scopus РИНЦ OpenAlex
A COMPLEX OF Zn(II) WITH CHIRAL NOPINANE-ANNELATED 9,9 '-bi-4,5-DIAZAFLUORENYLIDENE: SYNTHESIS, STRUCTURE, AND PROPERTIES
Journal of Structural Chemistry. 2020. V.61. N10. P.1606-1614. DOI: 10.1134/S0022476620100133 WOS Scopus РИНЦ OpenAlex
Original:
Кокина Т.Е.
, Глинская Л.А.
, Пирязев Д.А.
, Васильев Е.С.
, Шелудякова Л.А.
, Рахманова М.И.
, Ткачев А.В.
Комплекс zn(ii) с хиральным нопинан-аннелированным 9,9-би-4,5-диазафлуоренилиденом: синтез, структура, свойства
Журнал структурной химии (J STRUCT CHEM+). 2020. Т.61. №10. С.1690-1699. DOI: 10.26902/JSC_id61853 РИНЦ OpenAlex
Комплекс zn(ii) с хиральным нопинан-аннелированным 9,9-би-4,5-диазафлуоренилиденом: синтез, структура, свойства
Журнал структурной химии (J STRUCT CHEM+). 2020. Т.61. №10. С.1690-1699. DOI: 10.26902/JSC_id61853 РИНЦ OpenAlex
Dates:
| Published print: | Oct 1, 2020 |
| Published online: | Oct 13, 2020 |
Identifiers:
| Web of science: | WOS:000598775100013 |
| Scopus: | 2-s2.0-85106797997 |
| Elibrary: | 46782701 |
| OpenAlex: | W3110872498 |