Cobalt(II) hexaiododimercurate(II) complex with epsilon-caprolactam: Synthesis and crystal structure

Cobalt(II) hexaiododimercurate(II) complex with epsilon-caprolactam: Synthesis and crystal structure Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2017, Volume: 62, Number: 2, Pages: 187-190 Pages count : 4 DOI: 10.1134/S0036023617020206

Authors

Tikhomirova A.V. ¹ , Bagryanskaya I.Yu. ^2,3 , Pervukhina N.V. ⁴ , Cherkasova T.G. ¹

Affiliations

1	(Данные Web of science) Kuzbass State Tech Univ, Ul Vesennyaya 28, Kemerovo 650000, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk Natl Res State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia
4	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia

The conditions of synthesis of a new binary complex salt [Co(Cpl)(6)][Hg2I6] (Cpl is epsilon-caprolactam epsilon-C6H11NO) have been developed, and its structure has been characterized. The salt crystallizes in triclinic system, space group , a = 10.1078(4) , b = 12.2680(5) , c = 13.0782(5) , alpha = 62.872(2)A degrees, beta = 72.394(2)A degrees, gamma = 76.834(2)A degrees, V = 1367.98(9) (3), Z = 1, and rho(calc) = 2.297 g/cm(3). The structure is insular and consists of isolated ions.

Tikhomirova A.V. , Bagryanskaya I.Y. , Pervukhina N.V. , Cherkasova T.G.
Cobalt(II) hexaiododimercurate(II) complex with epsilon-caprolactam: Synthesis and crystal structure
Russian Journal of Inorganic Chemistry. 2017. V.62. N2. P.187-190. DOI: 10.1134/S0036023617020206 WOS Scopus РИНЦ OpenAlex

Тихомирова А.В. , Багрянская И.Ю. , Первухина Н.В. , Черкасова Т.Г.
СИНТЕЗ И КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА ГЕКСАИОДОДИМЕРКУРАТА(II) КОМПЛЕКСА КОБАЛЬТА(II) С ε-КАПРОЛАКТАМОМ
Журнал органической химии (RUSS J ORG CHEM+). 2017. Т.62. №2. С.193-196. DOI: 10.7868/S0044457X17020209 РИНЦ OpenAlex

Published print:	Feb 1, 2017
Published online:	Feb 25, 2017

Web of science:	WOS:000395029300008
Scopus:	2-s2.0-85013920974
Elibrary:	29486532
OpenAlex:	W2589939646

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