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3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals Full article

Journal Mendeleev Communications
ISSN: 0959-9436
Output data Year: 2017, Volume: 27, Number: 1, Pages: 19-22 Pages count : 4 DOI: 10.1016/j.mencom.2017.01.005
Authors Volkova Yulia M. 1 , Makarov Alexander Yu. 1 , Zikirin Samat B. 2,3 , Genaev Alexander M. 1 , Bagryanskaya Irina Yu. 1,4 , Zibarev Andrey V. 1,5
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Russian Acad Sci, Siberian Branch, VV Voevodsky Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
3 (Данные Web of science) Novosibirsk State Univ, Dept Phys, Novosibirsk 630090, Russia
4 (Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
5 (Данные Web of science) Tomsk State Univ, Dept Chem, Tomsk 634050, Russia

Abstract: The archetypal 3,1,2,4-benzothiaselenadiazine, its 5- and 8-Me3Si derivatives and related dithiadiazine and trithiadiazepine were synthesized from 2-Me3SiC6H4N=S=NSiMe3 by the action of SeCl2, SeCl4, SCl2, and S2Cl2 and converted into persistent 2,1,3-benzothiaselenazolyl and 1,2,3-benzodithiazolyl radicals characterized by EPR spectroscopy and DFT calculations.
Cite: Volkova Y.M. , Makarov A.Y. , Zikirin S.B. , Genaev A.M. , Bagryanskaya I.Y. , Zibarev A.V.
3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals
Mendeleev Communications. 2017. V.27. N1. P.19-22. DOI: 10.1016/j.mencom.2017.01.005 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Jan 1, 2017
Identifiers:
Web of science: WOS:000393539000005
Scopus: 2-s2.0-85010370200
Elibrary: 29476685
OpenAlex: W2580080600
Citing:
DB Citing
Web of science 16
Scopus 16
Elibrary 12
OpenAlex 15
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