Structure of molecular cocrystals of 18-crown-6 and polyhalogeno-meta-phenylenediamines Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2016, Volume: 57, Number: 6, Pages: 1225-1234 Pages count : 10 DOI: 10.1134/S002247661606024X | ||||
| Tags | molecular crystals; supramolecular architecture; single crystal X-ray diffraction analysis; polyfluorinated compounds; aromatic diamines; 18-crown-6 ether; functional materials | ||||
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Abstract:
A motif of the supramolecular architecture of ND 3/4 crystals of 18-crown-6 and polychloropolyfluoro-1,3- phenylenediamines or partially fluorinated 1,3-phenylenediamines (1:1 stoichiometry) is infinite 1D ensembles of alternating components. The mutual coordination of molecules in the ensembles is due to the hydrogen bond between crown ether oxygen atoms and hydrogen atoms of polyfluoroarene amino groups. Parameters of the architecture of ND 3/4 crystals are determined by the effect of the number and arrangement of substituents (chlorine and fluorine atoms) in the polyhalogenated aromatic ring.
Cite:
Vaganova T.A.
, Gatilov Y.V.
, Rodionov V.I.
, Malykhin E.V.
Structure of molecular cocrystals of 18-crown-6 and polyhalogeno-meta-phenylenediamines
Journal of Structural Chemistry. 2016. V.57. N6. P.1225-1234. DOI: 10.1134/S002247661606024X WOS Scopus РИНЦ OpenAlex
Structure of molecular cocrystals of 18-crown-6 and polyhalogeno-meta-phenylenediamines
Journal of Structural Chemistry. 2016. V.57. N6. P.1225-1234. DOI: 10.1134/S002247661606024X WOS Scopus РИНЦ OpenAlex
Original:
Ваганова Т.А.
, Гатилов Ю.В.
, Родионов В.И.
, Малыхин Е.В.
Структура молекулярных сокристаллов 18-краун-6 и полигалогено-мета-фенилендиаминов
Журнал структурной химии (J STRUCT CHEM+). 2016. Т.57. №6. С.1288-1298. DOI: 10.15372/JSC20160624 РИНЦ OpenAlex
Структура молекулярных сокристаллов 18-краун-6 и полигалогено-мета-фенилендиаминов
Журнал структурной химии (J STRUCT CHEM+). 2016. Т.57. №6. С.1288-1298. DOI: 10.15372/JSC20160624 РИНЦ OpenAlex
Dates:
| Published print: | Nov 1, 2016 |
| Published online: | Jan 24, 2017 |
Identifiers:
| Web of science: | WOS:000392615700024 |
| Scopus: | 2-s2.0-85010686500 |
| Elibrary: | 29476843 |
| OpenAlex: | W2583034692 |