Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene

Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene Научная публикация

Журнал

Molecules
, E-ISSN: 1420-3049

Вых. Данные

Год: 2021, Том: 26, Номер: 3, Номер статьи : 526, Страниц : DOI: 10.3390/molecules26030526

Ключевые слова

perfluorinated tetrathiacalix[4]arene; perfluoro-m-xylene; dioxadithiacalix[4]arenes; tetraoxadithiacalix[6]arene; thiourea; 2; 5-difluoro-4; 6-bis(trifluoromethyl)benzene-1; 3-dithiol; X-ray analyses

Авторы

Kovtonyuk Vladimir N. ¹ , Gatilov Yuri V. ¹ , Nikul'shin Pavel V. ¹ , Bredikhin Roman A. ¹

Организации

1	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Academician Lavrentjev Ave, Novosibirsk 630090, Russia

Perfluorinated tetrathiacalix[4]arene was obtained by heating perfluoro-m-xylene with thiourea or 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol at 90 degrees C. Interaction of perfluoro-m-xylene with resorcinol or orcinol under mild conditions and subsequent heating of the mixture with 2,5-difluoro-4,6-bis(trifluoromethyl)benzene-1,3-dithiol leads to polyfluorinated dioxadithiacalix[4]arenes. Triphenyl and pentaphenyl ethers formed by the interaction of perfluoro-m-xylene with resorcinol under heating with thiourea gives polyfluorinated oxathiacalixarenes containing six and five aromatic nuclei, respectively.

Kovtonyuk V.N. , Gatilov Y.V. , Nikul'shin P.V. , Bredikhin R.A.
Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene

Molecules. 2021. V.26. N3. 526 . DOI: 10.3390/molecules26030526 WOS Scopus РИНЦ OpenAlex

Полный текст от издателя

Опубликована online:

20 янв. 2021 г.

Web of science:	WOS:000615460700001
Scopus:	2-s2.0-85100480243
РИНЦ:	46745294
OpenAlex:	W3122502936

БД	Цитирований
Web of science	3
Scopus	3
РИНЦ	3
OpenAlex	3