Transformations of perfluorinated 1,2-dialkyl-, 1,1-and 1,2-alkylphenylbenzocyclobutenes to indan-2-one and isochromene derivatives under the action of CO/SbF5 Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2016, Volume: 188, Pages: 117-125 Pages count : 9 DOI: 10.1016/j.jfluchem.2016.06.014 | ||||
| Tags | Carbonylation; Carbocation; Perfluorinated; Benzocyclobutene; Indanone; Isochromene; Carbon monoxide; Antimony pentafluoride | ||||
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Abstract:
Interaction of perfluorinated 1,2-dialkylbenzocyclobutenes with CO-SbF5 at room temperature and perfluoro-1-methyl-2-phenylbenzocyclobutene at 50 degrees C gives fluoroindan-2-one derivatives. When reaction temperature is raised to 70 degrees C, polyfluorinated isochromene derivatives are formed in both cases. Interaction of perfluoro-1-ethyl-l-phenylbenzocyclobutene with CO-SbF5 at 70 degrees C gives, after treatment of the reaction mixture with H2O, perfluoro-3-ethyl-3-phenylindan-1,2-dione. (C) 2016 Elsevier B.V. All rights reserved.
Cite:
Zonov Y.V.
, Karpov V.M.
, Mezhenkova T.V.
, Rybalova T.V.
, Gatilov Y.V.
, Platonov V.E.
Transformations of perfluorinated 1,2-dialkyl-, 1,1-and 1,2-alkylphenylbenzocyclobutenes to indan-2-one and isochromene derivatives under the action of CO/SbF5
Journal of Fluorine Chemistry. 2016. V.188. P.117-125. DOI: 10.1016/j.jfluchem.2016.06.014 WOS Scopus РИНЦ OpenAlex
Transformations of perfluorinated 1,2-dialkyl-, 1,1-and 1,2-alkylphenylbenzocyclobutenes to indan-2-one and isochromene derivatives under the action of CO/SbF5
Journal of Fluorine Chemistry. 2016. V.188. P.117-125. DOI: 10.1016/j.jfluchem.2016.06.014 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Aug 1, 2016 |
Identifiers:
| Web of science: | WOS:000381836000018 |
| Scopus: | 2-s2.0-84978963499 |
| Elibrary: | 27091204 |
| OpenAlex: | W2541104782 |