Reaction of aryl(diarylphosphoryl)methanols with alkyl propiolates. Regio- and stereoselective synthesis of functional vinyl ethers

Reaction of aryl(diarylphosphoryl)methanols with alkyl propiolates. Regio- and stereoselective synthesis of functional vinyl ethers Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2016, Volume: 52, Number: 6, Pages: 772-776 Pages count : 5 DOI: 10.1134/S1070428016060026

Authors

Ivanova N.I. ¹ , Volkov P.A. ¹ , Khrapova K.O. ¹ , Larina L.I. ¹ , Bagryanskaya I.Yu. ^2,3 , Gusarova N.K. ¹ , Trofimov B.A. ¹

Affiliations

1	Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia
2	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia
3	Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

Aryl(diarylphosphoryl)methanols reacted with alkyl propiolates under mild conditions (triethylamine, THF, 22aEuro'25A degrees C), to give the corresponding anti-Markovnikov adducts, alkyl (E)-3-[aryl(diarylphosphoryl) methoxy]prop-2-enoates, with high yields (84-90%) and regio- and stereoselectivity.

Ivanova N.I. , Volkov P.A. , Khrapova K.O. , Larina L.I. , Bagryanskaya I.Y. , Gusarova N.K. , Trofimov B.A.
Reaction of aryl(diarylphosphoryl)methanols with alkyl propiolates. Regio- and stereoselective synthesis of functional vinyl ethers
Russian Journal of Organic Chemistry. 2016. V.52. N6. P.772-776. DOI: 10.1134/S1070428016060026 WOS Scopus РИНЦ OpenAlex

Иванова Н.И. , Волков П.А. , Храпова К.О. , Ларина Л.И. , Багрянская И.Ю. , Гусарова Н.К. , Трофимов Б.А.
Реакция (диарилфосфорил)(арил)метанолов с алкилпропиолатами. регио- и стереоселективный синтез функциональных виниловых эфиров
Журнал органической химии (RUSS J ORG CHEM+). 2016. Т.52. №6. С.788-792. РИНЦ

Published print:	Jun 1, 2016
Published online:	Jul 24, 2016

Web of science:	WOS:000380211600002
Scopus:	2-s2.0-84979302769
Elibrary:	27094755
OpenAlex:	W2495710232

DB	Citing
Web of science	5
Scopus	5
Elibrary	4
OpenAlex	4