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Click synthesis of triazole-linked polyazamacrocycles through selective isopimaric acid transformations Full article

Journal Macroheterocycles
ISSN: 1998-9539
Output data Year: 2021, Volume: 14, Number: 1, Pages: 105-111 Pages count : 7 DOI: 10.6060/mhc200817s
Tags CuAAC-reaction; Dialkynes; Diazides; Diterpenoids; Isopimaric acid; Macrocycles
Authors Gromova M.A. 1 , Kharitonov Yu.V. 2 , Rybalova T.V. 2 , Shults E.E. 2
Affiliations
1 Novosibirsk State Pedagogical University
2 Novosibirsk Institute of Organic Chemistry SB RAS

Abstract: The first macrocyclic pimarane type diterpenoids containing fragments of 1,2,3-triazole and tricyclic diterpenoid isopimaric acid moieties were synthesized. The key step was the CuAAC reaction of various diazides with the dialkyne derivative obtained from 16-(carboxyphenyl)isopimaric acid. The molecular structure of the macrocyclic compound with 1,5-diazopentane unit was determined by single crystal X-ray diffraction analysis.
Cite: Gromova M.A. , Kharitonov Y.V. , Rybalova T.V. , Shults E.E.
Click synthesis of triazole-linked polyazamacrocycles through selective isopimaric acid transformations
Macroheterocycles. 2021. V.14. N1. P.105-111. DOI: 10.6060/mhc200817s WOS Scopus РИНЦ OpenAlex
Files: Full text from publisher
Identifiers:
Web of science: WOS:000659682000012
Scopus: 2-s2.0-85108643262
Elibrary: 46155970
OpenAlex: W3174085912
Citing:
DB Citing
Elibrary 6
Web of science 2
Scopus 3
OpenAlex 3
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