X-ray induced phase transitions in 4-((4-(dibutylamino)phenyl)diazeny1)-biphenyl-2,3 ',4 '-tricarbonitrile

X-ray induced phase transitions in 4-((4-(dibutylamino)phenyl)diazeny1)-biphenyl-2,3 ',4 '-tricarbonitrile Научная публикация

Журнал

Journal of Molecular Structure
ISSN: 0022-2860 , E-ISSN: 1872-8014

Вых. Данные

Год: 2016, Том: 1107, Страницы: 242-248 Страниц : 7 DOI: 10.1016/j.molstruc.2015.11.060

Ключевые слова

Azobenzenes; X-ray induced transitions; Photoelectric effect; Mesophase texture

Авторы

Selivanova G.A. ¹ , Tretyakov E.V. ^1,2 , Amosov E.V. ¹ , Bagryanskaya I.Yu ^1,2 , Vasiliev V.G. ¹ , Vasilyev E.V. ¹ , Tikhova V.D. ¹ , Karpova E.V. ^1,2 , Basova T.V. ^2,3 , Stass D.V. ⁴ , Shteingarts V.D. ¹

Организации

1	(Данные Web of science) Vorozhtsov Inst Organ Chem, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia
3	(Данные Web of science) Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
4	(Данные Web of science) Voevodsky Inst Chem Kinet & Combust, Novosibirsk, Russia

Phase transitions in a glassy film of 4((4-(dibutylamino)phenyl)diazenyl)-biphenyl-2,3',4'-tricarbonitrile was initiated by a monochromatic X-ray microbeam with lambda = 0.71 angstrom (MoK alpha). At the site of the film that was directly impacted by irradiation noticeable morphological changes immediately occurred with subsequent crystal formation. From the site of irradiation, the front of transition of the glassy film into a liquid crystal phase propagated isotropically in all directions. This phenomenon is reproducible and clearly observed in the film prepared by heating the azo compound until melting and cooling it down to room temperature. These results highlight the fact that X-rays can be used as a tool to stimulate phase transitions in glassy azo compounds, which could also give birth to new and unexpected discoveries. (C) 2015 Elsevier B.V. All rights reserved.

Selivanova G.A. , Tretyakov E.V. , Amosov E.V. , Bagryanskaya I.Y. , Vasiliev V.G. , Vasilyev E.V. , Tikhova V.D. , Karpova E.V. , Basova T.V. , Stass D.V. , Shteingarts V.D.
X-ray induced phase transitions in 4-((4-(dibutylamino)phenyl)diazeny1)-biphenyl-2,3 ',4 '-tricarbonitrile
Journal of Molecular Structure. 2016. V.1107. P.242-248. DOI: 10.1016/j.molstruc.2015.11.060 WOS Scopus РИНЦ OpenAlex

Опубликована в печати:

1 мар. 2016 г.

Web of science:	WOS:000368954200030
Scopus:	2-s2.0-84948697907
РИНЦ:	25160967
OpenAlex:	W2172795880

БД	Цитирований
Web of science	6
Scopus	6
РИНЦ	7
OpenAlex	4