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beta-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect Full article

Journal RSC Advances
ISSN: 2046-2069
Output data Year: 2016, Volume: 6, Number: 7, Pages: 5653-5670 Pages count : DOI: 10.1039/c5ra23521a
Authors Audran Gerard 1 , Bosco Lionel 1 , Bremond Paul 1 , Butscher Teddy 1 , Franconi Jean-Michel 2 , Kabitaev Kuanysh 1 , Marque Sylvain R. A. 1,3 , Mellet Philippe 2,4 , Parzy Elodie 2 , Santelli Maurice 1 , Thiaudiere Eric 2 , Viel Stephane 1,5
Affiliations
1 (Данные Web of science) Aix Marseille Univ, CNRS, UMR 7273, ICR, Case 541,Ave Escadrille Normandie Niemen, F-13397 Marseille 20, France
2 (Данные Web of science) Univ Bordeaux 2, CNRS, UMR 5536, CRMSB, 146 Rue Leo Saignat,Case 93, F-33076 Bordeaux, France
3 (Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, Pr Lavrentjeva 9, Novosibirsk 630090, Russia
4 (Данные Web of science) INSERM, 146 Rue Leo Saignat,Case 93, F-33076 Bordeaux, France
5 (Данные Web of science) Inst Univ France, F-75000 Paris, France

Abstract: Recently, we published the titration of water in organic solvents and conversely using this family of nitroxides (Org. Biomol. Chem. 2015 ASAP). In this article, we show that the a(beta,P) of persistent cyclic beta-phosphorylated nitroxides decreases with the normalized polarity Reichardt's constant E-T(N). Koppel-Palm and Kalmet-Abboud-Taft relationships were applied to get a deeper insight into the effects influencing a(N) and a(beta,P): polarity/polarizability, hydrogen bond donor property, and structuredness of the cybotactic region.
Cite: Audran G. , Bosco L. , Bremond P. , Butscher T. , Franconi J-M. , Kabitaev K. , Marque S.R.A. , Mellet P. , Parzy E. , Santelli M. , Thiaudiere E. , Viel S.
beta-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect
RSC Advances. 2016. V.6. N7. P.5653-5670. DOI: 10.1039/c5ra23521a WOS Scopus РИНЦ OpenAlex
Files: Full text from publisher
Identifiers:
Web of science: WOS:000368941700060
Scopus: 2-s2.0-84955613426
Elibrary: 26856490
OpenAlex: W2297986638
Citing:
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Web of science 8
Scopus 8
Elibrary 8
OpenAlex 6
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