Unusual transformations of aliphatic nitro compounds in a flow reactor in high-pressure isopropanol on alumina. Part 2. Formation of esters

Unusual transformations of aliphatic nitro compounds in a flow reactor in high-pressure isopropanol on alumina. Part 2. Formation of esters Full article

Journal

Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162

Output data

Year: 2016, Volume: 107, Pages: 179-181 Pages count : 3 DOI: 10.1016/j.supflu.2015.08.007

Tags

Nitropentane; Nitrooctane; Isopropanol; Alumina; Esters; Octanenitrile; Nitrile

Authors

Sivcev V.P. ¹ , Volcho K.P. ^2,3 , Salakhutdinov N.F. ^2,3 , Anikeev V.I. ¹

Affiliations

1	(Данные Web of science) SB RAS, Boreskov Inst Catalysis, Novosibirsk, Russia
2	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

The reactivity of 1-nitropentane and 1-nitrooctane in supercritical isopropanol in a flow reactor in the presence of Al2O3 has been studied for the first time. In both reactions, isopropyl esters of respective acids were the main reaction products; their contents increased with increasing temperature. In case of 1-nitrooctane, the reaction mixture contained considerable amount of octanenitrile. (C) 2015 Elsevier B.V. All rights reserved.

Sivcev V.P. , Volcho K.P. , Salakhutdinov N.F. , Anikeev V.I.
Unusual transformations of aliphatic nitro compounds in a flow reactor in high-pressure isopropanol on alumina. Part 2. Formation of esters
Journal of Supercritical Fluids. 2016. V.107. P.179-181. DOI: 10.1016/j.supflu.2015.08.007 WOS Scopus РИНЦ OpenAlex

Published print:

Jan 1, 2016

Web of science:	WOS:000366077100022
Scopus:	2-s2.0-84942772449
Elibrary:	24934311
OpenAlex:	W1079276013

DB	Citing
Web of science	3
Scopus	3
Elibrary	3
OpenAlex	3