Mechanistic investigation of superelectrophilic activation of 1,1 '-bi-2-naphthols in the presence of aluminum halides Научная публикация
| Журнал |
Organic and Biomolecular Chemistry
ISSN: 1477-0520 , E-ISSN: 1477-0539 |
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| Вых. Данные | Год: 2019, Том: 17, Номер: 16, Страницы: 3971-3977 Страниц : 7 DOI: 10.1039/c9ob00640k | ||||||||
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Реферат:
7,7'-Dihydroxy-1,1'-bi-2-naphthol, as a result of superelectrophilic activation in the presence of an excess of aluminum halides, reacts with cyclohexane and benzene to yield 5,6,7,8,5', 6', 7', 8'-octahydro-7,7'-dioxo-bi-2-naphthol and its 5,5'-diphenyl derivative, respectively. In contrast, isomeric 6,6'-dihydroxy-1,1'-bi-2-naphthol does not react at all under the same reaction conditions, while the parent 1,1'-bi-2-naphthol (BINOL) reveals an alternative mode of behavior. The mechanistic aspects of these intriguing results are discussed on the basis of experimental and theoretical (DFT) study of the protonation and complexation properties of the starting BINOLs.
Библиографическая ссылка:
Zhu Z.
, Genaev A.M.
, Salnikov G.E.
, Koltunov K.Y.
Mechanistic investigation of superelectrophilic activation of 1,1 '-bi-2-naphthols in the presence of aluminum halides
Organic and Biomolecular Chemistry. 2019. V.17. N16. P.3971-3977. DOI: 10.1039/c9ob00640k WOS Scopus РИНЦ OpenAlex
Mechanistic investigation of superelectrophilic activation of 1,1 '-bi-2-naphthols in the presence of aluminum halides
Organic and Biomolecular Chemistry. 2019. V.17. N16. P.3971-3977. DOI: 10.1039/c9ob00640k WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000466500800010 |
| Scopus: | 2-s2.0-85064695674 |
| РИНЦ: | 38675000 |
| OpenAlex: | W2924789713 |