Реферат: Transesterification of R-substituted phenyl benzoates 1-5 with 4-methoxyphenol 6 was kinetically investigated in the presence of K2CO3 in dimethylformamide (DMF) at various temperatures. The Hammett plots for the reactions of the 1-5 demonstrate good linear correlations with sigma(0) constants. Low magnitude of (LG) values indicate that the leaving group departure occurs after the rate-determining step. The BrOnsted coefficient values for the reactions (-0.2, -0.16, -0.13 at 15, 24, 36 degrees C, respectively) demonstrate the weak effect of leaving group substituent on the reactivity of R-substituted phenyl benzoates 1-5 for the reactions with 4-methoxyphenol 6 in the presence of K2CO3 in DMF. The leaving group substituent effect on free energy (G), enthalpy (H), and entropy (S) of activation was examined. It was shown that the activation parameters obtained depend weakly on the leaving group substituent effect. The reaction is entropy controlled in case the leaving group substituent becomes electron withdrawing.

Библиографическая ссылка: Os'kina I.A.
Transesterification Kinetics Investigation of R-Substituted Phenyl Benzoates with 4-Methoxyphenol in the Presence of K2CO3 in DMF
International Journal of Chemical Kinetics. 2014. V.46. N1. P.24-30. DOI: 10.1002/kin.20822 WOS Scopus

Даты:

Опубликована online:	5 окт. 2013 г.
Опубликована в печати:	1 янв. 2014 г.

Идентификаторы:

Web of science	WOS:000327220500003
Scopus	2-s2.0-84888374906
OpenAlex	W2146168085

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