Sciact
  • EN
  • RU

Extraction-spectrophotometric determination of selenium in organoselenium compounds using aromatic o-diamines Научная публикация

Журнал Journal of Analytical Chemistry
ISSN: 1061-9348 , E-ISSN: 1608-3199
Вых. Данные Год: 2014, Том: 69, Номер: 5, Страницы: 432-437 Страниц : DOI: 10.1134/S1061934814030034
Ключевые слова organoselenium compounds; spectrophotometry; 1,2-diamino-3,4,5,6-tetrafluorobenzene; 2,3-diaminonaphthalene
Авторы Fadeeva V. P. 1 , Panin D. O. 2 , Nikulicheva O. N. 1 , Tikhova V. D. 1
Организации
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Реферат: Procedures for the extraction-spectrophotometric determination of selenium in organoselenium compounds using a new reagent, 1,2-diamino-3,4,5,6-tetrafluorobenzene (DAFB), and a known reagent, 2,3-diaminonaphthalene (DAN), are developed. Complexes of DAFB or DAN with selenium(IV) are extracted with toluene, and the absorbance of the extracts is measured. The optimal conditions for the determination were found, and the spectrophotometric characteristics were determined. The calibration curves are linear in the range of selenium concentrations of 1-10.6 mg/L (DAFB) and 1-9.1 mg/L (DAN). Nitrogen, chlorine, bromine, fluorine, and sulfur present in organoselenium compounds do not interfere with the determination of selenium. The relative error of determination does not exceed +/- 2%.
Библиографическая ссылка: Fadeeva V.P. , Panin D.O. , Nikulicheva O.N. , Tikhova V.D.
Extraction-spectrophotometric determination of selenium in organoselenium compounds using aromatic o-diamines
Journal of Analytical Chemistry. 2014. V.69. N5. P.432-437. DOI: 10.1134/S1061934814030034 WOS Scopus РИНЦ
Даты:
Опубликована online: 25 апр. 2014 г.
Опубликована в печати: 1 мая 2014 г.
Идентификаторы:
Web of science WOS:000335385600006
Scopus 2-s2.0-84901056074
РИНЦ 21880308
OpenAlex W2004725814
Альметрики: