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Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure Научная публикация

Журнал Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Вых. Данные Год: 2014, Том: 388, Номер: SI, Страницы: 162-166 Страниц : DOI: 10.1016/j.molcata.2013.09.016
Ключевые слова Pinene epoxide; Verbenol epoxide; Isomerization; Titania; Gold
Авторы Demidova Yu. S. 1 , Ardashov O. V. 2 , Simakova O. A. 3,4 , Simakova I. L. 1 , Volcho K. P. 2 , Salakhutdinov N. F. 2 , Murzin D. Yu. 3
Организации
1 (Данные Web of science) Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk Organ Chem Inst, Novosibirsk 630090, Russia
3 (Данные Web of science) Abo Akad Univ, Proc Chem Ctr, FI-20500 Turku, Finland
4 (Данные Web of science) Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA

Реферат: A novel method of (1S,2R,3R,5R)-6,6-dimethy1-4-methylenebicyclo[3.1.1]heptane-2,3-diol synthesis, which is a valuable intermediate in the synthesis of a perspective potent anti-Parkinson drugs, in the presence of TiO2 was proposed. Catalytic activity of TiO2 in the bicyclic terpene epoxides isomerization to corresponding allylic alcohols without changing of the initial structure was demonstrated, contrary to titania-supported Au catalysts which promoted rearrangement with predominant formation of a cyclopentene alpha-hydroxy ketone. (C) 2013 Elsevier B.V. All rights reserved.
Библиографическая ссылка: Demidova Y.S. , Ardashov O.V. , Simakova O.A. , Simakova I.L. , Volcho K.P. , Salakhutdinov N.F. , Murzin D.Y.
Isomerization of bicyclic terpene epoxides into allylic alcohols without changing of the initial structure
Journal of Molecular Catalysis A: Chemical. 2014. V.388. NSI. P.162-166. DOI: 10.1016/j.molcata.2013.09.016 WOS Scopus РИНЦ
Даты:
Опубликована в печати: 1 июл. 2014 г.
Идентификаторы:
Web of science WOS:000337551800019
Scopus 2-s2.0-84901324308
РИНЦ 22049548
OpenAlex W2066430198
Альметрики: