8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene

8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene Научная публикация

Журнал

MolBank
ISSN: 1422-8599

Вых. Данные

Год: 2021, Том: 2021, Номер: 4, Номер статьи : M1286, Страниц : DOI: 10.3390/M1286

Ключевые слова

BODIPY; Methylmagnesium iodide; Photoremovable protecting group; Tertiary alcohol

Авторы

Zobnina Anastasiya ¹ , Moskalensky Alexander ¹ , Vorob’ev Aleksey ^1,2

Организации

1	Department of Physics, Novosibirsk State University, 1 Pirogov Street, Novosibirsk, 630090, Russian Federation
2	Novosibirsk Institute of Organic Chemistry, 9 Lavrentiev avenue, Novosibirsk, 630090, Russian Federation

During recent years, the BODIPY core became a popular scaffold for designing photo-removable protecting groups (PPG). In this paper, we report the synthesis of a new mole-cule—8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐boron‐3a,4a‐diaza‐S‐indacene —by the treatment of meso‐(4‐CO2Me‐phenyl)‐BODIPY with excess of MeMgI. The product was characterized by1H,13C NMR and HRMS. The combination of BODIPY core with tertiary benzilyc alcohol might be promising for utilizing this molecule as visible light removable PPG. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

Zobnina A. , Moskalensky A. , Vorob’ev A.
8‐[4‐(2‐hydroxypropane‐2‐yl)phenyl]‐1,3,4,4,5,7‐hexamethyl‐4‐ boron‐3a,4a‐diaza‐s‐indacene
MolBank. 2021. V.2021. N4. M1286 . DOI: 10.3390/M1286 WOS Scopus РИНЦ

Web of science	WOS:000735584900001
Scopus	2-s2.0-85117348147
РИНЦ	47514380
OpenAlex	W3205241609