Mechanochemical synthesis of organohalogen compounds: a synthetic chemist's view

Mechanochemical synthesis of organohalogen compounds: a synthetic chemist's view Научная публикация

Журнал

Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837

Вых. Данные

Год: 2023, Том: 92, Номер: 9, Номер статьи : 5091, Страниц : DOI: 10.59761/rcr5091

Ключевые слова

mechanochemistry, halogenation, selectivity, reaction mechanism, green chemistry

Авторы

Borodkin Gennady Ivanovich ¹

Организации

1	N.N.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, prosp. Akademika Lavrentieva 9, 630090 Novosibirsk, Russian Federation

Data on the mechanochemical synthesis of halogen-containing organic compounds published mainly over the past 10 years are summarized and critically analyzed. The established views about the methods of activation of mechanochemical halogenation reactions are discussed. The mechanochemical fluorination, chlorination, bromination and iodination reactions of organic compounds are considered. Particular attention is paid to reaction mechanisms, selectivity problem and consideration of the mechanochemical approach as a promising trend of green chemistry. The review is devoted to applications of mechanochemistry in organic synthesis, while the fundamentals of mechanochemistry are beyond the scope of this publication. The bibliography includes 155 references.

Borodkin G.I.
Mechanochemical synthesis of organohalogen compounds: a synthetic chemist's view
Russian Chemical Reviews. 2023. V.92. N9. 5091 . DOI: 10.59761/rcr5091 WOS Scopus РИНЦ

Бородкин Г.И.
Механохимический синтез галогенорганических соединений: взгляд синтетика
Успехи химии/Uspekhi Khimii. 2023. Т.92. №9. 5091 .

Поступила в редакцию:	9 июн. 2023 г.
Опубликована в печати:	25 сент. 2023 г.
Опубликована online:	25 сент. 2023 г.

Web of science	WOS:001078593100002
Scopus	EID:2-s2.0-85173179136
РИНЦ	54519540
OpenAlex	W4385957938