X-ray emission and X-ray photoelectron study of the electronic structure of paramagnetic and diamagnetic derivatives of 3-imidazoline

X-ray emission and X-ray photoelectron study of the electronic structure of paramagnetic and diamagnetic derivatives of 3-imidazoline Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Вых. Данные

Год: 2014, Том: 55, Номер: 6, Страницы: 1044-1056 Страниц : 13 DOI: 10.1134/S0022476614060079

Ключевые слова

free nitroxyl radicals; 3-imidazoline derivatives; X-ray photoelectron spectroscopy; X-ray emission spectroscopy; effective charges; spin density

Авторы

Mazalov L.N. ^1,4 , Fedorenko A.D. ¹ , Kryuchkova N.A. ^1,4 , Dikov Yu.P. ² , Polienko Yu.F. ³ , Grigor'ev I.A. ³

Организации

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Geol Ore Deposits Petrog Mineral & Geochem, Moscow, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia
4	(Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia

X-ray emission spectra of oxygen OK (alpha) and X-ray photoelectron O1s spectra are obtained for stable nitroxyl radicals: 3-imidazoline derivatives and their diamagnetic derivatives. It is shown that the highest occupied molecular orbitals in the nitroxyl radicals mainly consist of oxygen and nitrogen 2p atomic orbitals of the nitroxyl group. Distinctions in the X-ray emission spectra of oxygen of the compounds studied can be due to the presence of the unpaired electron in the radicals.

Mazalov L.N. , Fedorenko A.D. , Kryuchkova N.A. , Dikov Y.P. , Polienko Y.F. , Grigor'ev I.A.
X-ray emission and X-ray photoelectron study of the electronic structure of paramagnetic and diamagnetic derivatives of 3-imidazoline
Journal of Structural Chemistry. 2014. V.55. N6. P.1044-1056. DOI: 10.1134/S0022476614060079 WOS Scopus РИНЦ

Мазалов Л.Н. , Федоренко А.Д. , Крючкова Н.А. , Диков Ю.П. , Полиенко Ю.Ф. , Григорьев И.А.
Рентгеноспектральное и рентгеноэлектронное изучение электронного строения парамагнитных и диамагнитных производных 3-имидазолина
Журнал структурной химии (J STRUCT CHEM+). 2014. Т.55. №6. С.1100-1113. РИНЦ

Опубликована в печати:	1 нояб. 2014 г.
Опубликована online:	24 янв. 2015 г.

Web of science	WOS:000348401200007
Scopus	2-s2.0-84921677506
РИНЦ	24030359
OpenAlex	W2081102757