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Strongly polarized surface electroluminescence from an organic light-emitting transistor Научная публикация

Журнал Materials Chemistry Frontiers
ISSN: 2052-1537
Вых. Данные Год: 2023, Том: 7, Номер: 2, Страницы: 238-248 Страниц : 11 DOI: 10.1039/d2qm01046a
Авторы Trukhanov Vasiliy A. 1,2 , Kuevda Alexey V. 1,2 , Dominskiy Dmitry I. 1,2 , Mannanov Artur L. 1,2 , Rybalova Tatyana V. 4 , Tafeenko Victor A. 5 , Sosorev Andrey Yu. 1,2 , Konstantinov Vladislav G. 1,2 , Kazantsev Maxim S. 4 , Borshchev Oleg V. 2 , Ponomarenko Sergey A. 2,5 , Pshenichnikov Maxim S. 3 , Paraschuk Dmitry Yu. 1,2
Организации
1 Московский государственный университет имени М.В. Ломоносова
2 Федеральное государственное бюджетное учреждение науки Институт синтетических полимерных материалов им.Н.С.Ениколопова Российской академии наук
3 Optical Condensed Matter Physics Group, Zernike Institute for Advanced Materials, Rijksuniversiteit Groningen
4 Новосибирский институт органической химии им. Н.Н. Ворожцова СО РАН
5 Московский государственный университет имени М.В. Ломоносова

Информация о финансировании (1)

1 Российский Научный Фонд 20-73-10090

Реферат: Emissive materials that radiate polarized light are in high demand for a broad variety of light-emitting electronic devices. In organic light-emitting devices—light-emitting diodes and transistors—highly polarized emission from the device surface, the surface emission, can be achieved by the in-plane co-linear orientation of molecular transition dipole moments (TDMs) in the device active layer. Furthermore, such a TDM arrangement strongly alleviates the waveguiding effect, enhancing the performance of the device. In this work, we report the first practical implementation of these ideas in an organic light-emitting transistor. Highly emissive semiconductor single crystals were grown from a thiophene–phenylene co-oligomer 1,4-bis{5-[4-(trimethylsilyl)phenyl]thiophen-2-yl}benzene (TMS-PTPTP-TMS) with trimethylsilyl (TMS) terminal substituents, which promote the in-plane TDM orientation. Organic light-emitting transistors based on TMS-PTPTP-TMS showed ambipolar charge transport with efficient electroluminescence, and the single-crystal devices demonstrated linearly polarized electroluminescence with the polarization degree of 0.78 ± 0.06. The observed polarization properties of both electro- and photoluminescence are in full agreement with the solved crystal structure and the corresponding calculations. Our findings indicate that smart control of in-plane ordered TDMs via molecular packing is a promising approach to designing materials for highly efficient light-emitting electronic devices.
Библиографическая ссылка: Trukhanov V.A. , Kuevda A.V. , Dominskiy D.I. , Mannanov A.L. , Rybalova T.V. , Tafeenko V.A. , Sosorev A.Y. , Konstantinov V.G. , Kazantsev M.S. , Borshchev O.V. , Ponomarenko S.A. , Pshenichnikov M.S. , Paraschuk D.Y.
Strongly polarized surface electroluminescence from an organic light-emitting transistor
Materials Chemistry Frontiers. 2023. V.7. N2. P.238-248. DOI: 10.1039/d2qm01046a WOS РИНЦ
Даты:
Принята к публикации: 28 нояб. 2022 г.
Опубликована online: 29 нояб. 2022 г.
Идентификаторы:
Web of science WOS:000894203000001
РИНЦ 60204719
OpenAlex W4311171175
Альметрики: