Bridged 1,3(1,5)-benzoxazocines and 1,3,5-benzoxadiazocines as products of the Hantzsch and Biginelli reactions Научная публикация
| Журнал |
Chemistry of Heterocyclic Compounds
ISSN: 0009-3122 , E-ISSN: 1573-8353 |
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| Вых. Данные | Год: 2022, Том: 58, Номер: 6-7, Страницы: 279-300 Страниц : 22 DOI: 10.1007/s10593-022-03085-8 | ||
| Ключевые слова | 2,6-methano-1,3-benzoxazocines 2,6-methano-1,3,5-benzoxadiazocines 2,6-methano-1,3,5-benzoxadiazocin-4-ones 2,6-methano-1,3,5-benzoxadiazocine-4-thiones salicylic aldehydes Biginelli reaction biological activity Hantzsch reaction intramolecular transformations | ||
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Реферат:
The use of substituted salicylaldehyde, a dicarbonyl compound, and a nitrogen base as starting compounds in the Hantzsch and Biginelli reactions leads to the formation of not only the expected reaction products, but also O-bridged derivatives isomeric to them. The review summarizes the results of studies of such Hantzsch and Biginelli reactions, as well as modified versions of these reactions with starting compounds, acid catalysts, and solvents of different nature. The routes of formation and chemical transformations of O-bridged structures, which represent the class of oxazocines and oxadiazocines with various substituents (H, Alk, Ar, Hal, OH, OAlk, NH2, etc.) and functional groups (Ac, CHO, CO2Alk, COCO2Alk, CONR2, CN, NO2), are discussed. Data on the biological activity of some functional derivatives are presented.
Библиографическая ссылка:
Shkurko O.P.
Bridged 1,3(1,5)-benzoxazocines and 1,3,5-benzoxadiazocines as products of the Hantzsch and Biginelli reactions
Chemistry of Heterocyclic Compounds. 2022. V.58. N6-7. P.279-300. DOI: 10.1007/s10593-022-03085-8 WOS РИНЦ
Bridged 1,3(1,5)-benzoxazocines and 1,3,5-benzoxadiazocines as products of the Hantzsch and Biginelli reactions
Chemistry of Heterocyclic Compounds. 2022. V.58. N6-7. P.279-300. DOI: 10.1007/s10593-022-03085-8 WOS РИНЦ
Оригинальная версия:
Шкурко О.П.
Мостиковые 1,3(1,5)-бензоксазоцины и 1,3,5-бензоксадиазоцины как продукты реакций Гранча и Биджинелли
Химия гетероциклических соединений/Khimiya Geterotsiklicheskikh Soedinenii. 2022. С.22.
Мостиковые 1,3(1,5)-бензоксазоцины и 1,3,5-бензоксадиазоцины как продукты реакций Гранча и Биджинелли
Химия гетероциклических соединений/Khimiya Geterotsiklicheskikh Soedinenii. 2022. С.22.
Даты:
| Поступила в редакцию: | 2 дек. 2021 г. |
| Принята к публикации: | 14 апр. 2022 г. |
| Опубликована online: | 30 июл. 2022 г. |
Идентификаторы:
| Web of science | WOS:000833454200007 |
| РИНЦ | 51468025 |
| OpenAlex | W4288748459 |