Synthesis, Structure and Emission Properties of [Cu-2(mu(2)-I)(2)L-4] Complex Based on 2-(Methylthio)Pyrazine

Synthesis, Structure and Emission Properties of [Cu-2(mu(2)-I)(2)L-4] Complex Based on 2-(Methylthio)Pyrazine Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Вых. Данные

Год: 2019, Том: 60, Номер: 6, Страницы: 967-971 Страниц : 5 DOI: 10.1134/S0022476619060118

Ключевые слова

copper(I); pyrazines; sulfide ligands; photoluminescence; crystal structure

Авторы

Artem'ev A.V. ^1,2 , Beresin A.S. ^1,2 , Bagryanskaya I.Yu. ^2,3

Организации

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu-2(mu(2)-I)(2)L-4], wherein CuCu contact of 2.6351(4) angstrom is observed. The each metal atom of the [Cu-2(mu(2)-I)(2)] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (lambda(max) = 600 nm) with the average lifetime of 1.66 mu s and quantum yield of 17%.

Artem'ev A.V. , Beresin A.S. , Bagryanskaya I.Y.
Synthesis, Structure and Emission Properties of [Cu-2(mu(2)-I)(2)L-4] Complex Based on 2-(Methylthio)Pyrazine
Journal of Structural Chemistry. 2019. V.60. N6. P.967-971. DOI: 10.1134/S0022476619060118 WOS Scopus РИНЦ

Artem'ev A.V. , Berezin A.S. , Bagryanskaya I.Y.
SYNTHESIS, STRUCTURE AND EMISSION PROPERTIES OF [CU2(M2-I)2L4] COMPLEX BASED ON 2-(METHYLTHIO)PYRAZINE
Журнал структурной химии (J STRUCT CHEM+). 2019. V.60. N6. P.1008-1012. DOI: 10.26902/JSC_id40732 РИНЦ

Опубликована в печати:	1 июн. 2019 г.
Опубликована online:	4 июл. 2019 г.

Web of science	WOS:000474373600011
Scopus	2-s2.0-85068769287
РИНЦ	41642596
OpenAlex	W2953512452