Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine

Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine Научная публикация

Журнал

Mendeleev Communications
ISSN: 0959-9436

Вых. Данные

Год: 2012, Том: 22, Номер: 1, Страницы: 18-20 Страниц : DOI: 10.1016/j.mencom.2012.01.006

Авторы

Artem'ev Alexander V. ¹ , Malysheva Svetlana F. ¹ , Sukhov Boris G. ¹ , Belogorlova Nataliya A. ¹ , Gatilov Yurii V. ² , Mamatyuk Victor I. ² , Gusarova Nina K. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Redox reaction between alkali metal diselenophosphinates R2P(Se)SeM (M = Na, K) and elemental iodine in a 2:1 molar ratio (1,4-dioxane, room temperature, 2 min) gives bis(diorganylselenophosphoryl)selenides [R2P(Se)](2)Se and bis(diorganylselenophosphoryl)triselenides [R2P(Se)](2)Se-3 in 87-90% total yields.

Artem'ev A.V. , Malysheva S.F. , Sukhov B.G. , Belogorlova N.A. , Gatilov Y.V. , Mamatyuk V.I. , Gusarova N.K.
Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine
Mendeleev Communications. 2012. V.22. N1. P.18-20. DOI: 10.1016/j.mencom.2012.01.006 WOS Scopus РИНЦ

Опубликована в печати:

1 янв. 2012 г.

Web of science	WOS:000301020400006
Scopus	2-s2.0-84856519863
РИНЦ	17975228
OpenAlex	W2041742929