Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation

Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation Научная публикация

Журнал

Journal of Fluorine Chemistry
ISSN: 0022-1139

Вых. Данные

Год: 2012, Том: 137, Страницы: 64-72 Страниц : DOI: 10.1016/j.jfluchem.2012.02.012

Ключевые слова

Polyfluoro-2-naphthylamines; Hydrodefluorination; CVA measurements; Quantum-chemical calculations; X-ray analysis

Авторы

Selivanova Galina A. ¹ , Reshetov Alexey V. ^1,2 , Beregovaya Irina V. ¹ , Vasil'eva Nadezhda V. ¹ , Bagryanskaya Irina Yu. ¹ , Shteingarts Vitalij D. ¹

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Div, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Hydrodefluorination of heptafluoro-2-naphthylamine and its less fluorinated analogues by zinc in aqueous ammonia has been explored with respect to the possibility to occur and to rationalize the product distribution in terms of the mechanism including formation and fragmentation of a polyfluoroarene radical anion. (c) 2012 Published by Elsevier B.V.

Selivanova G.A. , Reshetov A.V. , Beregovaya I.V. , Vasil'eva N.V. , Bagryanskaya I.Y. , Shteingarts V.D.
Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation
Journal of Fluorine Chemistry. 2012. V.137. P.64-72. DOI: 10.1016/j.jfluchem.2012.02.012 WOS Scopus РИНЦ

Опубликована в печати:

1 мая 2012 г.

Web of science	WOS:000304179700008
Scopus	2-s2.0-84859562826
РИНЦ	17982256
OpenAlex	W2062338252